How to Determine Parameters for Hydrogen Transition Probability?

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SUMMARY

The discussion focuses on calculating the parameters of the potential (\epsilon, \alpha, \tau) for a hydrogen atom transitioning from the |100> state to any n=2 state under a weak, uniform electric field described by E(t) = \epsilon e^{-\alpha t / \tau}. The transition probability formula is derived as P = \gamma^2 \epsilon^2 \left| \int_0^{T \gg \tau} e^{-\left( \frac{3i}{4} + \frac{\alpha}{\tau}\right)t} dt \right|^2, where \gamma^2 = \frac{2^{15}}{3^{10}}. The user expresses confusion over determining three parameters from a single equation, but guidance from a teacher suggests focusing on the z-direction for the electric field to simplify the transition to the |210> state.

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svletana
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Hello! I have the following problem I'm trying to solve:

Homework Statement


An Hydrogen atom in the state |100> is found between the plates of a capacitor, where the electric field (weak and uniform) is: E(t) = \epsilon e^{-\alpha t / \tau}.

Calculate the parameters of the potential (\epsilon, \alpha, \tau) so that for a time t \gg \tau the transition probability to any of the n=2 states is equal to 0.1.

Homework Equations


The field is asumed to be in an arbitrary r = (x,y,z) direction, so that W = \epsilon e^{-\alpha t / \tau} r.

The formula for transition probability is (using atomic units):
P = \left| \int_0^{T \gg \tau} e^{i \omega t} <100 | r | 21m> \epsilon e^{-\alpha t / \tau}dt \right|^2

where \omega = \frac{E_{21m} - E_{100}}{\hbar} = \frac{-3}{4}.

For the <100|r|21m> elements we have the results, for each m:
<100|r|200> = 0
<100|r|210> = \frac{2^7 \sqrt{2} \hat{z}}{3^5}
<100|r|21\pm1> = \frac{2^7}{3^5}(\mp\hat{x} - i\hat{y})

The Attempt at a Solution


I solved the integral for an arbitrary m and l=1, calling the result of the <100|r|21m>=\gamma. Since it does not depend on t we can take it out of the integral along with all the constants. The integral is then:

P = \gamma^2 \epsilon^2 \left| \int_0^{T \gg \tau} e^{-\left( \frac{3i}{4} + \frac{\alpha}{\tau}\right)t} dt \right|^2

For which I solved and took the limit T \rightarrow \infty and got the result:

\frac{\gamma^2 \epsilon^2}{\frac{9}{16} + \frac{\alpha^2}{\tau^2}}

Now, \gamma^2 = \frac{2^{15}}{3^{10}} for any value of m. And that result must be equal to 0.1 according to the guidelines.

I don't see how I could possibly calculate 3 parameters from this equation, what am I missing? Thanks in advance!
 
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Not that this is that much help but shouldn't the potential be proportional to r \cos \theta not r? With this you get zero for m=-1, but the same otherwise.
 
Dazed&Confused said:
Not that this is that much help but shouldn't the potential be proportional to r \cos \theta not r? With this you get zero for m=-1, but the same otherwise.

Sorry, r would be a vector, for example r = xî + yĵ + zk, so you could have it in any of the three directions.
 
Ah ok. It's just I would have thought you take the inner product of the potential, that is, the potential is your operator.
 
I just talked to my teacher and he said that i should choose the field going in the z direction so the only transition possible is to the |210> state and then choose parameters that would fit the problem... Guess that settles it :P
 
But I'm also not sure how you can get 3 parameters from one equation. It is strange that it says for any n=2 state though, when at least if l=1, m=0, you got 0 as the probability. Also perhaps that the electric field is weak needs to be employed.
 
Well that's what I did, hence z = r \cos \theta, however to me that didn't give an obvious solution.
 
Would the parameters \alpha = 3.67 \times 10^7, \epsilon = 1.93 \times 10^{11} \frac{V}{m} and \tau = 1.109 \times 10^{-9} seconds work?

I had in mind that it would have to be an electric field strong enough to make the transition but not so big so hydrogen is ionized, a value of \tau around the value of the half life for that transition, and calculating \alpha with those two and the expression.
 
That sounds reasonable. The wording of question doesn't imply you have some freedom in choosing your parameters, but since the number of equations is under determined I would say you are likely right.
 
  • #10
Yeah I only really found out because I emailed my teacher asking how would I get 3 parameters from one equation, but that's exactly what he wrote...

Thanks for your help! :)
 

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