Involving Rate determining steps

  • Thread starter Thread starter Foon
  • Start date Start date
  • Tags Tags
    Rate
Click For Summary
SUMMARY

The discussion centers on determining the rate-determining steps in a chemical reaction mechanism involving the equation 2A + B --> 2E + F. The experimentally determined rate law is Rate = k[A][B], indicating a second-order reaction with respect to A and first-order with respect to B. The proposed mechanism includes a first step where A and B react to form an intermediate C and product F, followed by a second step where A converts to C- and produces 2E. The intermediate C is not present in the final reaction, confirming its role as a transient species.

PREREQUISITES
  • Understanding of chemical kinetics and rate laws
  • Familiarity with reaction mechanisms and intermediates
  • Knowledge of elementary reactions and their characteristics
  • Ability to analyze and manipulate chemical equations
NEXT STEPS
  • Study the concept of rate-determining steps in reaction mechanisms
  • Learn about the role of intermediates in chemical reactions
  • Explore the derivation of rate laws from proposed reaction mechanisms
  • Investigate the implications of reaction order on chemical kinetics
USEFUL FOR

Chemistry students, educators, and professionals involved in chemical kinetics and reaction mechanism analysis will benefit from this discussion.

Foon
Messages
5
Reaction score
0
I have no idea how to figure this one out, I've been hacking away at it all evening. Please help :frown:

Consider the general reaction:

2A + B --> 2E + F

The experimentally determined rate law equation is written as follows:

Rate = k[A]

A proposed mechanism for the reaction has the first step below:

Step 1: A + B --> C + F (rate determinging step)

Assuming a two-step mechanism, write a possible second elementary reaction for this mechanism.


And this is what I have but I'm not sure if its right. And I'm totally puzzled as to how they get rid of the C.

Step1: A + B --> C + F
Step2: A --> C- + 2E
------------------------
2A + B --> 2E + F

It has to be totally wrong since they've given me a rate law which I have no idea how to use.
 
Chemistry news on Phys.org
HW, so this is going to be a step at a time: 1) what's the ORDER of the reaction --- you've got a rate expression; 2) what else does the rate expression tell you; 3) WHAT is "C"?
 
You're almost there. For the second equation put C on the left side. That should do it.
 
Do what meninger said. C is the intermediate in the reaction, therefore it can't be in the final product at all.
 
I came.across a headline and read some of the article, so I was curious. Scientists discover that gold is a 'reactive metal' by accidentally creating a new material in the lab https://www.earth.com/news/discovery-that-gold-is-reactive-metal-by-creating-gold-hydride-in-lab-experiment/ From SLAC - A SLAC team unexpectedly formed gold hydride in an experiment that could pave the way for studying materials under extreme conditions like those found inside certain planets and stars undergoing...

Similar threads

  • · Replies 2 ·
Replies
2
Views
3K
  • · Replies 1 ·
Replies
1
Views
2K
  • · Replies 3 ·
Replies
3
Views
2K
  • · Replies 3 ·
Replies
3
Views
6K
Replies
15
Views
4K
Replies
10
Views
5K
Replies
7
Views
2K
  • · Replies 4 ·
Replies
4
Views
4K
  • · Replies 6 ·
Replies
6
Views
2K
  • · Replies 8 ·
Replies
8
Views
4K