Is BH3 a Lewis Base in Reaction with NH3?

  • Thread starter Thread starter terryds
  • Start date Start date
  • Tags Tags
    Acid Base
Click For Summary
SUMMARY

In the reaction between borane (BH3) and ammonia (NH3), BH3 acts as a Lewis base while NH3 functions as a Lewis acid. This conclusion is drawn from the electronegativity values: nitrogen (N) has an electronegativity of 3.0, which is higher than boron (B) at 2.0, indicating that NH3 can accept electrons more readily than BH3. The Lewis structures reveal that NH3 has a lone pair of electrons available for donation, confirming its role as a Lewis acid in this interaction.

PREREQUISITES
  • Understanding of Lewis acid-base theory
  • Knowledge of electronegativity values
  • Ability to draw Lewis structures
  • Familiarity with basic chemical bonding concepts
NEXT STEPS
  • Study the properties of Lewis acids and bases in organic chemistry
  • Learn how to draw and interpret Lewis structures for complex molecules
  • Research the role of empty orbitals in determining Lewis acidity
  • Explore examples of Lewis acid-base reactions in coordination chemistry
USEFUL FOR

Chemistry students, educators, and anyone interested in understanding Lewis acid-base theory and its applications in chemical reactions.

terryds
Messages
392
Reaction score
13

Homework Statement



In the reaction with NH3, is specy BH3 a Lewis base ?

Homework Equations


Lewis acid = electron acceptor
Lewis base = electron donor

The Attempt at a Solution



H electronegativity = 2.1
B electronegativity = 2.0
N electronegativity = 3
Since N-H bond is more electronegative than B-H bond, NH3 is more electronegative than BH3 which means that NH3 is more easily to accept electron. So, NH3 is Lewis acid, BH3 is Lewis base

Is it correct??
My book says that NH3 is the base with no reason, and I doubt that.
 
Physics news on Phys.org
A good way to analyse the above problem would be to draw the Lewis structures.There is a reason it is named after G.N. Lewis!
 
sidt36 said:
A good way to analyse the above problem would be to draw the Lewis structures.There is a reason it is named after G.N. Lewis!

Alright,
Based on Lewis structure, NH3 have three pair of bonding electrons and one pair of free electrons while BF3 have three pair of bonding electrons.

and then? How to determine which one is base or acid ?
 
So the electron configuration is something like this
Untitled.png


So i think this might help
 
  • Like
Likes   Reactions: terryds
My teacher Told me if it has an empty orbital ->Lewis acid
Otherwise its most likely ->Lewis base
 
  • Like
Likes   Reactions: terryds
Thanks! I got it!
 
Last edited:

Similar threads

  • · Replies 1 ·
Replies
1
Views
2K
  • · Replies 26 ·
Replies
26
Views
7K
  • · Replies 3 ·
Replies
3
Views
2K
  • · Replies 1 ·
Replies
1
Views
2K
Replies
1
Views
2K
Replies
3
Views
6K
  • · Replies 3 ·
Replies
3
Views
5K
  • · Replies 5 ·
Replies
5
Views
2K
Replies
3
Views
2K
  • · Replies 6 ·
Replies
6
Views
5K