Is BH3 a Lewis Base in Reaction with NH3?

  • Thread starter Thread starter terryds
  • Start date Start date
  • Tags Tags
    Acid Base
Click For Summary

Discussion Overview

The discussion revolves around whether BH3 acts as a Lewis base in its reaction with NH3. Participants explore the definitions of Lewis acids and bases, analyze electronegativity, and consider Lewis structures to understand the interaction between these species.

Discussion Character

  • Homework-related
  • Conceptual clarification
  • Debate/contested

Main Points Raised

  • One participant suggests that because NH3 is more electronegative than BH3, it should be considered the Lewis acid, while BH3 would be the Lewis base.
  • Another participant proposes that drawing Lewis structures could clarify the roles of NH3 and BH3 in the reaction.
  • A later reply mentions that NH3 has three pairs of bonding electrons and one pair of free electrons, while BH3 has three pairs of bonding electrons, prompting a question about how to determine which is the acid or base.
  • One participant shares a teacher's insight that a species with an empty orbital is likely a Lewis acid, while one without is likely a Lewis base.
  • Another participant expresses satisfaction with the information provided, indicating some understanding of the topic.

Areas of Agreement / Disagreement

Participants do not reach a consensus on whether BH3 is a Lewis base. Multiple viewpoints are presented regarding the definitions and roles of the species involved, indicating ongoing debate.

Contextual Notes

Limitations include the reliance on electronegativity comparisons and Lewis structures, which may not fully resolve the question of acid-base behavior in this context.

terryds
Messages
392
Reaction score
13

Homework Statement



In the reaction with NH3, is specy BH3 a Lewis base ?

Homework Equations


Lewis acid = electron acceptor
Lewis base = electron donor

The Attempt at a Solution



H electronegativity = 2.1
B electronegativity = 2.0
N electronegativity = 3
Since N-H bond is more electronegative than B-H bond, NH3 is more electronegative than BH3 which means that NH3 is more easily to accept electron. So, NH3 is Lewis acid, BH3 is Lewis base

Is it correct??
My book says that NH3 is the base with no reason, and I doubt that.
 
Physics news on Phys.org
A good way to analyse the above problem would be to draw the Lewis structures.There is a reason it is named after G.N. Lewis!
 
sidt36 said:
A good way to analyse the above problem would be to draw the Lewis structures.There is a reason it is named after G.N. Lewis!

Alright,
Based on Lewis structure, NH3 have three pair of bonding electrons and one pair of free electrons while BF3 have three pair of bonding electrons.

and then? How to determine which one is base or acid ?
 
So the electron configuration is something like this
Untitled.png


So i think this might help
 
  • Like
Likes   Reactions: terryds
My teacher Told me if it has an empty orbital ->Lewis acid
Otherwise its most likely ->Lewis base
 
  • Like
Likes   Reactions: terryds
Thanks! I got it!
 
Last edited:

Similar threads

  • · Replies 1 ·
Replies
1
Views
2K
  • · Replies 26 ·
Replies
26
Views
7K
  • · Replies 3 ·
Replies
3
Views
2K
  • · Replies 1 ·
Replies
1
Views
2K
Replies
1
Views
3K
Replies
3
Views
6K
  • · Replies 3 ·
Replies
3
Views
5K
  • · Replies 5 ·
Replies
5
Views
2K
Replies
3
Views
2K
  • · Replies 6 ·
Replies
6
Views
5K