What are the dangers of breathing pure oxygen while diving?

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SUMMARY

Breathing pure oxygen while diving poses significant risks, primarily due to oxygen toxicity, which can lead to central nervous system effects such as seizures and convulsions. Divers typically use gas mixtures like Nitrox (32% or 38% oxygen) for depths up to 40 meters, while deeper dives require Heliox or Trimix to mitigate nitrogen narcosis and oxygen toxicity. The maximum safe partial pressure of oxygen is generally 1.6 atm underwater, with higher pressures necessitating careful gas management to avoid dangerous situations. Oxygen exposure limits are critical, as prolonged use of 100% oxygen can irritate the lungs and lead to cumulative toxic effects.

PREREQUISITES
  • Understanding of oxygen toxicity and its physiological effects
  • Knowledge of diving gas mixtures, specifically Nitrox, Heliox, and Trimix
  • Familiarity with partial pressure concepts in diving
  • Awareness of nitrogen narcosis and its implications for deep diving
NEXT STEPS
  • Research the physiological effects of oxygen toxicity in diving scenarios
  • Learn about the composition and use of Nitrox for recreational diving
  • Study the advantages and disadvantages of Heliox and Trimix for deep-sea diving
  • Investigate safe diving practices and exposure limits for oxygen in underwater environments
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Diving instructors, scuba divers, medical professionals involved in hyperbaric medicine, and anyone interested in the safety protocols of deep-sea diving.

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I've heard that breathing pure oxygen is bad for you, but I can't find any information about it online. Is it bad?

Do scuba divers and astronauts breathe pure oxygen or is it diluted with other gases?
 
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Oxygen poisoning.

Too high partial pressure in the air leads to seizures and blackouts, together with uncontrolled cotractions of muscles.

You can still breathe pure oxygen, just its pressure must be low enough.
 
Even when a patient is put 'on oxygen', the gas they are breathing is not pure oxygen, it just has a higher % in it. The lungs are generally very efficient at getting oxygen out of the air and into the blood;I heard that the red blood cells leaving the lungs are about 98% saturated with it, so breathing more oxygen is not going to do a huge deal of good to a healthy person.
 
I've asked a few docs about this at work, it does seem counterintuitive that too high a percentage oxygen is just as bad as too low a percentage. We decided that the problem is that a too-high O2 concentration displaces CO2 in the blood and tissues; this changes the pH- and that is the problem: an off-nominal pH.
 
Could be - no idea what the physiological mechanism is, but I have seen results at work.

In fact it is enough to hyperventillate for a few minutes to start to feel uncontrolled contractions of muscles - lips at first.
 
Andy Resnick said:
I've asked a few docs about this at work, it does seem counterintuitive that too high a percentage oxygen is just as bad as too low a percentage. We decided that the problem is that a too-high O2 concentration displaces CO2 in the blood and tissues; this changes the pH- and that is the problem: an off-nominal pH.

I never gave it considerable thought before, but that makes sense. I was thinking along the lines that Borek was, that without a CO2 signal, hyperventillation would be a problem.

Since the OP also asked about divers, I think the O2 is displaced with nitrogen for divers as they head into deeper depths.
 
Moonbear said:
Since the OP also asked about divers, I think the O2 is displaced with nitrogen for divers as they head into deeper depths.

When you go deeper nitrogen becomes dangerous as well (see nitrogen narcosis) - thus you don't use nitrogen to dilute oxygen, rather other gases with lower molecular mass (these times in form of mixtures, like trimix or heliox).
 
Borek said:
When you go deeper nitrogen becomes dangerous as well (see nitrogen narcosis) - thus you don't use nitrogen to dilute oxygen, rather other gases with lower molecular mass (these times in form of mixtures, like trimix or heliox).

Oh, right, helium is definitely in the mix for very deep sea diving. I was watching some show where they had guys working pretty deep to repair oil rigs at sea, and as they communicated with the people on the platform, their voices were all squeaky. It was pretty hilarious, because they were all these big, burly, oil rig working, deep sea diving, manly men type people and talking in these funny, squeaky, high-pitched voices from the helium.
 
Yeah Nitrogen narcolepsy kicks in at around 120-150 ft (3.5-4.5 atmospheres) depending on the person's physiology, so it can't be used for depths below that. I've personally gotten nitrogen narcolepsy at 140 ft before, it felt kind of like being drunk and giddy at the same time.
 
  • #10
You only need a partial pressure 0.2atm oxygen to function normally.
You are supposed to only use 100% O2 for a maximum of 24hours, but this is mainly because it irritates the lungs. Most hospital masks are designed to also allow some room air in so you aren't breathing 100% O2
Medical and aircraft bottled oxygen is often 70% O2 (the rest nitrogen) but that's mainly for fire prevention, there are a bunch of plastics and grease/oil that combust in 100% O2.

Higher oxygen partial pressures cause entertaining central nervous system toxicity effects, like convulsions. The limit for O2 in dangerous situations (like underwater) is generally 1.6atm but you can use upto around 3.2atm on the surface in a chamber for short periods.

In diving, down to normal recreational depths (40m) the best thing to use it Nitrox - air with enhanced O2 either 32 or 38% O2. Below 40m Nitrogen narcosis becomes a problem which is why it's the limit for recreational scuba.
Below that you have to remove the nitrogen and replace it with helium = Heliox.

As you go deeper to the point that 21% oxygen would get above 1.6atm you also have to remove some of the oxygen. That gets dangerous because you then have a mix that doesn't have enough oxygen to breathe at shallower depths, so as you descend you have to swap systems. It's a bit safer in commercial diving where someone at the surface (who hopefully isn't as stressed, disorientated and narced) is handling the mixes.

Then as you get much deeper (below 2-300m) helium starts to cause the same CNS symptoms as O2 and you have to replace some of the helium with hydrogen = trimix. With this you can work at 800m!

ps. guess who used to be a diving instructor
 
  • #11
I'm not sure that concentration of CO2 triggers breathing, I think it's just partial pressure. There are some people with a low sensitivity to CO2 who need a high concentration to trigger a breath - when you give them oxygen they pass out !
 
  • #12
mgb_phys said:
You only need a partial pressure 0.2atm oxygen to function normally.
You are supposed to only use 100% O2 for a maximum of 24hours, but this is mainly because it irritates the lungs. Most hospital masks are designed to also allow some room air in so you aren't breathing 100% O2
Medical and aircraft bottled oxygen is often 70% O2 (the rest nitrogen) but that's mainly for fire prevention, there are a bunch of plastics and grease/oil that combust in 100% O2.

Higher oxygen partial pressures cause entertaining central nervous system toxicity effects, like convulsions. The limit for O2 in dangerous situations (like underwater) is generally 1.6atm but you can use upto around 3.2atm on the surface in a chamber for short periods.

In diving, down to normal recreational depths (40m) the best thing to use it Nitrox - air with enhanced O2 either 32 or 38% O2. Below 40m Nitrogen narcosis becomes a problem which is why it's the limit for recreational scuba.
Below that you have to remove the nitrogen and replace it with helium = Heliox.

As you go deeper to the point that 21% oxygen would get above 1.6atm you also have to remove some of the oxygen. That gets dangerous because you then have a mix that doesn't have enough oxygen to breathe at shallower depths, so as you descend you have to swap systems. It's a bit safer in commercial diving where someone at the surface (who hopefully isn't as stressed, disorientated and narced) is handling the mixes.

Then as you get much deeper (below 2-300m) helium starts to cause the same CNS symptoms as O2 and you have to replace some of the helium with hydrogen = trimix. With this you can work at 800m!

ps. guess who used to be a diving instructor

Diving Heliox is too expensive and not really needed under 40m , Trimix (He,N2,02)is ok and used at depth over 40m all time. Its completely safe. In fact I am not sure of anyone dives Heliox nowadays in tech diving, save maybe for very deep phases in special situations.

There are diving agencies who now aggressively promote hyperoxic Trimix for any dives where you would use Nitrox traditionally.

H2 + 02 mix is called Hydrox not "Trimix" ; H2+02+He is called Hydreliox.

Helium toxicity and related HPNS syndrome can occur af depths of more than 120m already. It is *better* to dive Trimix than Heliox after this depth. Even a low percent of N2 greatly helps to limit helium toxicity. Trimix is considered safe to depths of ~180m.

I don't recall the depths for exotic gases containing hydrogen.For the OP:

pure oxygen is used in diving only for shallow decompression stops. To prevent accumulation of oxtox units, very often "gas breaks" are performed, usually in a pattern like 12 min on 02 / 6 min on a helium mix with lowest possible 02 for the deep.

Oxygen presents both pulmonary and CNS toxic effects. It is important to note that the toxic effect is *cumulative* this is important in diving. There are maximum amounts of exposure you can safely get / 24h.
 
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