There is "friction", a phenomenon, and there is the "friction force". The first is neither vector nor scalar. The second is a vector, as any type of force.
Same as "gravity" is a phenomenon and the weight or "force of gravity" is a force. People (especially students) tend to use "gravity" when they mean the force of attraction.
This is OK in general but it may create confusion sometimes.
Multiplying the friction by a unit vector (or by anything else) is not a valid operation.
You can multiply the magnitude of the friction force by a unit vector, if you wish. Indeed the friction force is tangent to the surfaces in contact.
And I think I understand (maybe) your problem.
If you look at the equation
Ff=μN, it makes sense for the magnitudes of the forces but not in vector form. The friction force is not parallel to the normal force.