Is metallic hydrogen superconductive at 273k

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Discussion Overview

The discussion centers around the potential superconductivity of metallic hydrogen at 273K, exploring whether it could be the highest temperature superconductor known. It involves theoretical predictions, experimental challenges, and the conditions necessary for metallic hydrogen to exhibit superconducting properties.

Discussion Character

  • Debate/contested
  • Technical explanation
  • Conceptual clarification

Main Points Raised

  • Some participants propose that metallic hydrogen may be a superconductor at temperatures up to room temperature (~290K), based on theoretical predictions from Ashcroft in 1968.
  • Others argue that no one has demonstrated metallic hydrogen as a superconductor, noting that all known phases are insulating and asserting it is not superconductive at 273K.
  • A participant mentions that the temperature of 273K is coincidentally equal to the freezing point of water, suggesting skepticism about it being a superconducting temperature.
  • There are claims regarding the extreme pressures required to maintain metallic hydrogen at high temperatures, with one participant stating that the pressure needed to keep hydrogen metallic at 290K would be enormous.
  • Experimental efforts have been made to measure electrical conductivity changes in metallic hydrogen, with findings indicating that the electronic energy band gap decreases significantly under high pressure.

Areas of Agreement / Disagreement

Participants generally disagree on the superconductivity of metallic hydrogen at 273K, with some asserting it is not superconductive while others reference theoretical predictions of high-temperature superconductivity. The discussion remains unresolved regarding the actual superconducting properties of metallic hydrogen.

Contextual Notes

Limitations include the lack of experimental verification of metallic hydrogen as a superconductor, dependence on high-pressure conditions, and the unresolved nature of the theoretical predictions regarding its superconductivity.

ensabah6
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and if so is it the highest temperature superconductor known?
 
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No one has -as far as I know- ever even demonstrated that metallic hydrogen is a superconductor (all known phases are insulating). It is most definitely not a superconductor at 273K

(which is a bit of a "silly" temperature anyway, it happens to be equal to 0 degrees Celsius which is also the freezing temperature of water; it would if nothing else be a HUGE coincidence if metallic H had a Tc of that temperature).
 

Wikipedia said:
Superconductivity:

In 1968, Ashcroft put forward that metallic hydrogen may be a superconductor, up to room temperature (~290 K), far higher than any other known candidate material. This stems from its extremely high speed of sound and the expected strong coupling between the conduction electrons and the lattice vibrations.

...The team had sought simply to measure the less extreme electrical conductivity changes which were expected to occur. The researchers used a 1960s-era light gas gun, originally employed in guided missile studies, to shoot an impactor plate into a sealed container containing a half-millimeter thick sample of liquid hydrogen. The liquid hydrogen was in contact with wires leading to a device measuring electrical resistance. The scientists found that, as pressure rose to 1.4E+6 atm (142 GPa), the electronic energy band gap, a measure of electrical resistance, fell to almost zero.
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Reference:
http://en.wikipedia.org/wiki/Metallic_hydrogen#Superconductivity"
 
Last edited by a moderator:
Yes, metallic hydrogen has been predicted to be superconducting at very high temperatures. But no one has actually shown that this prediction is correct.
Also, the pressure needed to keep the hydrogen metallic at 290K would be truly enormous.
 

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