Is there an Entropy difference between a cold and hot body

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Discussion Overview

The discussion revolves around the concept of entropy in the context of two bodies at different temperatures coming into thermal contact. Participants explore the changes in entropy during this process, the implications of negative entropy values, and the calculations involved in determining the final temperature and entropy of the system.

Discussion Character

  • Exploratory
  • Technical explanation
  • Conceptual clarification
  • Debate/contested

Main Points Raised

  • One participant inquires about the entropy of a system when two bodies at different temperatures reach thermal equilibrium.
  • Another participant questions whether the discussion is focused on changes in entropy or absolute entropy values.
  • It is suggested that the cold body experiences an increase in entropy while the hot body experiences a decrease, with the overall entropy of the system increasing due to thermal conduction.
  • Some participants mention the equation for calculating change in entropy, indicating that it involves reversible heat transfer.
  • Concerns are raised about the negative sign in entropy calculations, with one participant suggesting that it indicates a decrease in entropy for a specific process.
  • There is a discussion about the first law of thermodynamics and its application to determine the final temperature of the system.
  • Participants express uncertainty about the derivation of equations related to internal energy and entropy changes.
  • Clarifications are sought regarding the assumptions made about the nature of the bodies involved (e.g., ideal gases vs. solids).

Areas of Agreement / Disagreement

Participants do not reach a consensus on several points, including the interpretation of entropy changes, the implications of negative entropy values, and the specific calculations required to determine the final temperature and entropy of the system.

Contextual Notes

Participants express uncertainty regarding the assumptions made in their calculations, such as whether the system is closed or the nature of the bodies involved. There are also unresolved questions about the derivation of certain equations related to internal energy and entropy.

  • #31
Mister T said:
Really? You can get all that from just the two initial temperatures? It makes no difference what the substances are, what their mass is, or what the final temperature is?
Of course you have to specify the masses and heat capacities of the two bodies. I think you must already have known that.
 
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  • #32
Chestermiller said:
Of course you have to specify the masses and heat capacities of the two bodies. I think you must already have known that.

Of course I did, which is why I said that without that information you wouldn't have enough information. But you claimed I was wrong when I did that!
 
  • #33
annaphys said:
Ah so you mean an isochor and isotherm and do this continuously until the cold body reaches the final temperature?
I can't understand why you feel compelled to place labels on the processes we are dealing with here, such as adiabatic, isochoric, constant temperature, isothermal, etc. Please stop doing this. The reversible process to take either of these bodies from its initial thermodynamic equilibrium state to its final thermodynamic equilibrium state is not isothermal (since the system temperature is changing), and, for an incompressible solid, the term isochoric is redundant.

If you mean that, to get the body from the initial to the final state reversibly, we can put the body into sequential contact with a series of constant temperature reservoirs at slightly different temperatures, running monotonically from the initial temperature to the final temperature, then this is correct. Is that what you meant?
 
  • #34
Mister T said:
Of course I did, which is why I said that without that information you wouldn't have enough information. But you claimed I was wrong when I did that!
I was unable to read your mind. You certainly didn't mention what information, if any, was missing.
 
  • #35
Chestermiller said:
I was unable to read your mind. You certainly didn't mention what information, if any, was missing.

Huhh? Everything, except what is given, is missing.

Here is the OP's question:
annaphys said:
If two bodies, who say start with ##T_{cold}=T_c## and ##T_{hot}=T_h## and then they are brought in contact with one another and then after some time they both have the same temperature. What would be the entropy of the entire system?

My response was to state that there is not enough information given to answer that question.

Your response to me was to contradict that, so I followed up with a clarification and now you are agreeing with me.
 
  • #36
annaphys said:
Where does this equation exactly come from? Why would the internal energy be zero when there is internal energy in the system? The difference in the internal energy is zero but nonetheless there is internal energy.
The internal energy isn't zero; the CHANGE in internal energy is zero!
 

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