Is there more than one definition of entropy?

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Discussion Overview

The discussion centers on the definitions of entropy, particularly in thermodynamics and statistical mechanics, and whether there is more than one definition of entropy. Participants explore the implications of these definitions in various contexts, including isolated systems and the behavior of particles under gravitational influence.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested

Main Points Raised

  • One participant notes their understanding of entropy is limited to the thermodynamic definition \(\Delta S = \int_1^2 \frac{dQ}{T}\) and questions if this is the only definition.
  • Another participant points out that the definitions of entropy in thermodynamics and statistical mechanics differ but yield the same value for large systems, suggesting that the definitions are not applicable to systems with only two bodies.
  • A participant mentions that the statistical mechanics definition \(S = k \ln \Omega\) can derive the thermodynamic definition but not vice versa, indicating a hierarchy in the definitions.
  • Concerns are raised about the behavior of two isolated iron spheres as they approach each other, with one participant asserting that their entropy does not increase and questioning the possibility of reversing their motion.
  • Another participant argues that entropy arguments are only valid for macroscopic systems and that movies of particle behavior can be reversed, although most scenarios increase entropy.
  • There is a discussion about the improbability of certain configurations of particles, with one participant acknowledging that while certain outcomes are improbable, they are not impossible.

Areas of Agreement / Disagreement

Participants express differing views on the definitions of entropy and their applicability to specific scenarios. There is no consensus on whether the entropy of the two spheres increases or on the implications of reversing motion in isolated systems.

Contextual Notes

Participants highlight limitations in applying entropy definitions to small systems and the dependence on the number of particles involved. The discussion also touches on the implications of gravitational effects on the behavior of isolated bodies.

fluidistic
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After having completed 2 years of a Bachelor's degree, the only definition of entropy I know is [tex]\Delta S = \int_1^2 \frac{dQ}{T}[/tex]. I realize it's the change of entropy rather than the entropy of a system.

My question is "Is this the only definition of entropy"? I've seen in wikipedia and Fundamentals of Physics (Resnick-Halliday) the definition [tex]S=k \ln \Omega[/tex] but I never learned it nor do I understand what it means.

In the case of 2 isolated iron spheres in the Universe that are separated by a distance d. When they get closer and closer to each other, does the entropy of the system (the 2 spheres) increases? With the definition I have from entropy, heat is not involved so the formula is not useful.
Because I realize that the 2 spheres will only get closer and closer and if I could record a film of the motion, I'd realize instantly if the film passes reversely or not.
Assuming that yes, entropy increases in the example... I have another question:

Do you buy that it's IMPOSSIBLE for a sphere not to get closer to the other?

It's different than in the case of having a gas confined into a 1 m^3 cube we want to know whether the film passes reversely or not. Because there is a small probability that say 10^24 particles are confined into 10 cm^3 rather than in 1m^3 which is the volume of the container. Hence looking at the film, although I could almost always be right in telling the direction of the film, I could still be wrong (ok, I realize this won't happen within a very large time, even much greater than the current age of the Universe but I consider this as a possibility-improbability and not as an impossibility).
I wrote the last paragraph to show a distinction between what I consider impossible and what I consider improbable but possible. I would like to know if it is possible but improbable that the 2 spheres reduce their acceleration even for a very short time when they're getting closer to each other. I believe it's impossible and would violate Newton's laws (I'm pretty sure that it would also violate Relativity ones).

Thanks for all.
 
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Hi.
The definitions of entropy in thermodynamics and of statistical mechanics are different but they give identical value to a system.
Both thermodynamics and statistical mechanics are for systems of great many particles. Both are not applicable in your case of only two bodies involved. Gravity between the bodies could make them closer.
Regards.
 
Last edited:
fluidistic said:
My question is "Is this the only definition of entropy"? I've seen in wikipedia and Fundamentals of Physics (Resnick-Halliday) the definition [tex]S=k \ln \Omega[/tex] but I never learned it nor do I understand what it means.
The second can be used to derive the first, but no vice versa (to my knowledge).
I posted an outline of the proof in
https://www.physicsforums.com/showthread.php?t=353528&page=2

You can also see
https://www.physicsforums.com/showthread.php?t=365823
first, to understand what the number of possible realizations [itex]\Omega[/itex] means.

You are right, that the first thermodynamics definition is useful for common thermodynamics only.

fluidistic said:
In the case of 2 isolated iron spheres in the Universe that are separated by a distance d. When they get closer and closer to each other, does the entropy of the system (the 2 spheres) increases? With the definition I have from entropy, heat is not involved so the formula is not useful.
In this example neither the entropy increases, nor is there an arrow of time. The iron sphere might well be together but have an outwards momentum, which would reverse the whole movie.

Entropy arguments only work for macroscopic systems and even then fail to a small extend. See the references given in
https://www.physicsforums.com/showthread.php?t=364225&page=2

And moreover a bunch of particles released in the corner of and empty room will return there after a very very long time. Movies may well be reversed, but it just happens that almost all of the possible movies increase entropy.

fluidistic said:
It's different than in the case of having a gas confined into a 1 m^3 cube we want to know whether the film passes reversely or not. Because there is a small probability that say 10^24 particles are confined into 10 cm^3 rather than in 1m^3 which is the volume of the container. Hence looking at the film, although I could almost always be right in telling the direction of the film, I could still be wrong (ok, I realize this won't happen within a very large time, even much greater than the current age of the Universe but I consider this as a possibility-improbability and not as an impossibility).
This is correct. For any other process it is even worse in the sense that the state-return-time is much shorter.
 
Ok thank you both. It's much clearer in my mind now.
 

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