Is This Wavefunction a Valid Solution for the Schrödinger Equation?

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SUMMARY

The wavefunction solution \(\psi(x,y,z) = Ae^{i\mathbf{k}\cdot\mathbf{r}}\) satisfies the time-independent Schrödinger equation \(\frac{\hbar^{2}}{2m}\Delta \psi(x,y,z) = E\,\psi(x,y,z)\). The relationship between the wavevector \(\mathbf{k}\) and energy \(E\) is given by \(\frac{E}{K} = \frac{\hbar^{2}}{2m}\), where \(K = k_x^{2} + k_y^{2} + k_z^{2}\). The time-dependent wavefunction can be expressed as the product of the spatial function \(\psi(x,y,z)\) and a time-dependent function \(f(t)\), which needs to be determined to fully solve the equation.

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beyondlight
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Homework Statement



Show that this solution:

\psi(x,y,z)=Ae^{i\mathbf{k}\cdot\mathbf{r}}

is a solution for this equation:

\frac{\hbar^{2}}{2m}\Delta \psi(x,y,z)=E\,\psi(x,y,z),

How is K related to E?

How does the corresponding timedependent function look like?



The Attempt at a Solution



My second derivative is:

\psi''(x,y,z)=i^{2}k_x^{2}A \cdot e^{ik_x*r} \cdot e^{ik_y*r} \cdot e^{ik_z*r} = -k_x^{2}A \cdot e^{ik_x*r} \cdot e^{ik_y*r} \cdot e^{ik_z*r}=-k_x^{2} \cdot \psi

\frac{\hbar^{2}}{2m}(k_x^{2} + k_y^{2} + k_z^{2}) \cdot \psi = E \cdot \psi

\frac{\hbar^{2}}{2m}(k_x^{2} + k_y^{2} + k_z^{2}) = E


I suppose it is enough to say that

\frac{\hbar^{2}}{2m} (k_x^{2} + k_y^{2} + k_z^{2}) is energy? So it automatically satisfies the S.E.? What is the unit of \psi?

But the relation between k and E should then be:

\frac{\hbar^{2}}{2m} \cdot (k_x^{2} + k_y^{2} + k_z^{2}) = \frac{\hbar^{2}}{2m} \cdot K = E

\frac{E}{K}= \frac{\hbar^{2}}{2m}


But the last task is a bit more tricky...I will just separate the time-depentent S.E.

\frac{\hbar^{2}}{2m}\Delta \psi = i\hbar \frac{d\psi}{dt}

\frac{\hbar^{2}}{2m}\Delta = i\hbar \frac{d\psi}{dt} \cdot \frac{1}{\psi}

Can someone help me from here?
 
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beyondlight said:

Homework Statement



Show that this solution:

\psi(x,y,z)=Ae^{i\mathbf{k}\cdot\mathbf{r}}

is a solution for this equation:

\frac{\hbar^{2}}{2m}\Delta \psi(x,y,z)=E\,\psi(x,y,z),

How is K related to E?

How does the corresponding timedependent function look like?



The Attempt at a Solution



My second derivative is:

\psi''(x,y,z)=i^{2}k_x^{2}A \cdot e^{ik_x*r} \cdot e^{ik_y*r} \cdot e^{ik_z*r} = -k_x^{2}A \cdot e^{ik_x*r} \cdot e^{ik_y*r} \cdot e^{ik_z*r}=-k_x^{2} \cdot \psi
Small correction: it really should be kxx, kyy, etc. here. And it looks like you are using ψ'' to mean ∂²ψ/∂x². But you have the right idea.

\frac{\hbar^{2}}{2m}(k_x^{2} + k_y^{2} + k_z^{2}) \cdot \psi = E \cdot \psi

\frac{\hbar^{2}}{2m}(k_x^{2} + k_y^{2} + k_z^{2}) = E


I suppose it is enough to say that

\frac{\hbar^{2}}{2m} (k_x^{2} + k_y^{2} + k_z^{2}) is energy? So it automatically satisfies the S.E.? What is the unit of \psi?

But the relation between k and E should then be:

\frac{\hbar^{2}}{2m} \cdot (k_x^{2} + k_y^{2} + k_z^{2}) = \frac{\hbar^{2}}{2m} \cdot K = E

\frac{E}{K}= \frac{\hbar^{2}}{2m}

Close, but not quite. You are saying that

k_x^2 + k_y^2 + k_z^2 = k^1 ?​

I think you need to modify the k1 term, slightly, to have a true statement here.

But the last task is a bit more tricky...I will just separate the time-depentent S.E.

\frac{\hbar^{2}}{2m}\Delta \psi = i\hbar \frac{d\psi}{dt}

\frac{\hbar^{2}}{2m}\Delta = i\hbar \frac{d\psi}{dt} \cdot \frac{1}{\psi}

Can someone help me from here?
Let's back up 1 step to

\frac{\hbar^{2}}{2m}\Delta \psi = i\hbar \frac{d\psi}{dt}

Since ψ is a function of (x,y,z) only, we really need another symbol for the time-dependent part. It's common to assume the full wavefunction is the product of a spatial function (that's ψ(x,y,z) ) and a time-dependent function (call it f(t)). So you want to put ψ(x,y,z)·f(t) into the time-dependent Schrödinger Equation, and work out what f(t) is.

Hope that helps. By the way, \partial will give you the partial derivative symbol in LaTeX.
 

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