Lattice constant and volume density

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SUMMARY

The discussion focuses on calculating the lattice constant and volume density for a body-centered lattice composed of two atoms, A with an effective radius of 2.00 angstroms and B with an effective radius of 3.10 angstroms. The correct lattice constant is determined to be 5.89 angstroms. However, the calculation for volume density is incorrect due to confusion between surface density and volume density, leading to an erroneous result of 9.79 x 10^21 atoms/cm² instead of the correct volume density calculation.

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  • Understanding of body-centered cubic (BCC) lattice structures
  • Knowledge of effective atomic radii and their implications in lattice calculations
  • Familiarity with the equations for surface density and volume density
  • Basic skills in unit conversion, particularly between angstroms and centimeters
NEXT STEPS
  • Study the derivation and application of the volume density formula in crystal structures
  • Learn about the differences between surface density and volume density in crystallography
  • Explore examples of body-centered cubic structures and their properties
  • Investigate the calculation of lattice constants for various crystal structures
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Students and professionals in materials science, crystallography, and solid-state physics who are involved in lattice structure analysis and density calculations.

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Homework Statement


a) A material is composed of two atoms, A with effecitve radius 2.00 angstroms and B with effective radius 3.10 angstroms. The lattice is a body-centred lattice.
b)Enter the volume density of either the A or B atoms in atoms/cm3

Homework Equations


.5*sqrt3=(r1+r2)
surface density=# of atoms per lattice plane/area of lattice plane

The Attempt at a Solution


a)
a=((3.10A+2.0A)*2)/(sqrt3)
a=5.89 A (Lattice constant) (correct)

b) In part B I keep getting the wrong answer.

The equation I'm using is surface density=# of atoms/area of lattice plane

So...
# of atoms should be 2 for a body centered cube
2/(5.89*10^-8)^3 = 9.79*10^21 atoms/cm^2 (incorrect)
 
Last edited:
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As far as I remember, body-centered here refers to the symmetry alone: the central atom has the same type as the corners, the other atoms are in between.

As an example, Caesium chloride would fit your calculation, but its crystal structure is simple cubic.

But then I'm surprised that the lattice constant is right.

Do you mix surface and volume density here?
 

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