Metals, X-rays, and plasma frequency

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Discussion Overview

The discussion revolves around the relationship between the plasma frequency of metals and the frequency at which X-rays begin to penetrate these materials. Participants explore whether the plasma frequency can be used to explain the transparency of metals to X-rays and other electromagnetic radiation, with a focus on theoretical and practical implications.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested
  • Mathematical reasoning

Main Points Raised

  • One participant suggests that the frequency at which X-rays penetrate a metal might correspond to the plasma frequency related to the electron density of the metal.
  • Another participant questions this idea, stating that plasmon energies are significantly lower than the X-ray range.
  • A participant proposes calculating the electron plasma frequency for copper, providing a specific value and expressing uncertainty about the effective mass of electrons and permittivity values used in the calculation.
  • There is a discussion about the nature of plasmons as charge density fluctuations in metals and their quantum mechanical treatment.
  • A later reply suggests that the plasma frequency could be relevant for understanding when metals become transparent to electromagnetic radiation, particularly in the UV range.

Areas of Agreement / Disagreement

Participants express differing views on the applicability of plasma frequency to X-ray penetration, with some arguing it is relevant while others contend it is not. The discussion remains unresolved regarding the exact relationship between plasma frequency and X-ray transparency.

Contextual Notes

Participants note limitations in their calculations, such as uncertainties in effective mass and permittivity values, which may affect the accuracy of the plasma frequency estimates.

pervect
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I was wondering if it would be fair to say that the frequency at which x-rays start to penetrate a metal would be the plasma frequency associated with the electron density of the metal, i.e. the frequency given by

http://scienceworld.wolfram.com/physics/PlasmaFrequency.html

or whether some other mechanism was involved.
 
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Have you tried calculating the electron plasma frequency for some typical metals?
 
you wouldn't be correct. plasmon energies are several orders of magnitude lower than the x-ray range.
 
Last edited:
Tide said:
Have you tried calculating the electron plasma frequency for some typical metals?

Using the MKS formula at

http://www.everything2.com/index.pl?node_id=1529021

and using N = 8.47 * 10^28 / m^3 for copper

http://hyperphysics.phy-astr.gsu.edu/HBASE/tables/fermi.html#c2

I am currently getting 2.6*10^15 hz

This seems to probably be a bit low, in the UV range. But I don't know what the effective mass of an electron in copper should be, nor do I know what the permittivity value should be - they probably shouldn't be the free-space values I used for both.

I also don't really know when copper starts transmitting x-rays, for that matter :-(.
 
inha said:
you wouldn't be correct. plasmon energies are several orders of magnitude lower than the x-ray range.

What's a plasmon?

It looks like the estimate in terms of plasma frequency misses the mark by a few orders of magnitude from remarks that have been made - any ideas of how can it be "fixed up" to get within, say, one order of magnitude?
 
plasmons are charge density fluctuations (collective excitations) in metals. same stuff but treated quantum mechanically taking the proper electronic structure into account. I don't think you can get much closer since in a lot of metals the electron effective masses aren't too far from the bare electron mass.
 
pervect said:
I was wondering if it would be fair to say that the frequency at which x-rays start to penetrate a metal would be the plasma frequency associated with the electron density of the metal, i.e. the frequency given by

http://scienceworld.wolfram.com/physics/PlasmaFrequency.html

or whether some other mechanism was involved.
If you are trying to calculate the frequency at which a metal starts to become transparent to radiation, that would be the plasma frequency. Most metals are transparent at high UV frequencies.

So, to correct the statement in your OP :
...it would be fair to say that the frequency at which EM radiation starts to penetrate a metal would be the plasma frequency associated with the electron density of the metal...
 
OK, that answers the question, thanks. And it nicely explains why the semiconductor people have trouble building UV mirrors, too.
 

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