Molecular Speeds in a Laboratory Apparatus

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SUMMARY

The discussion focuses on calculating molecular speeds in a laboratory apparatus containing an ideal gas with a molecular mass of 50 x 10^-3 kg/mol. Key calculations include the average speed, root mean square (rms) speed, and most probable speed based on the given speed distribution: 10% at 200 m/s, 10% at 250 m/s, 15% at 500 m/s, 30% at 650 m/s, 20% at 900 m/s, and 15% at 1300 m/s. The average speed is calculated by summing the weighted speeds and dividing by the total number of molecules, while the rms speed is derived from the squared speeds. The most probable speed corresponds to the speed with the highest percentage of molecules, which is 650 m/s. Finally, the temperature of the gas is determined using the formula T = M(Vrms^2)/(3R).

PREREQUISITES
  • Understanding of ideal gas laws
  • Familiarity with statistical distributions in physics
  • Knowledge of root mean square (rms) calculations
  • Basic algebra for solving equations
NEXT STEPS
  • Learn how to derive the average speed of gas molecules in different distributions
  • Study the concept of root mean square speed in thermodynamics
  • Explore the relationship between molecular speed and temperature in ideal gases
  • Investigate statistical mechanics and its applications in gas behavior
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Physics students, educators, and researchers interested in molecular dynamics, thermodynamics, and statistical mechanics will benefit from this discussion.

zferic28
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A physics student measures molecular speeds in a laboratory apparatus and concludes that the distribution of speeds is such that:
10% have a speed of 200 m/s
10% gave a speed of 250m/s
15% have a speed of 500m/s
30% have a speed of 650m/s
20% have a speed of 900m/s
15% have a speed of 1300 m/s

Calculate
a) the average speed
b) the rms speed
c)the most probable speed
Assuming that the apparatus contains and ideal gas with the molecular mass m = 50 x 10^-3 kg/mol, and the above distribution of speeds
d) determine the temperature of the gas in the apparatus

a) The precentages throw me off in this problem. I know that to find the average speed, I need to add up all the speeds^2 and divide by the total number of molecules.

[(1 x 200m/s) + (1 x 250m/s) + (1.5 x 500 m/s)+ (3.0 x 650 m/s) + (2 x 900m/s) + (1.5 x 1300m/s)]/10



b) [(1 x 200m/s)^2 + (1 x 250m/s)^2 + (1.5 x 500 m/s)^2 + (3.0 x 650 m/s)^2 + (2 x 900m/s)^2 + (1.5 x 1300m/s)^2]/10

=1.15x 10^6 m^2/s^2


The rms speed = sqrt(1.15x 10^6 m^2/s^2)

c) I really don't know what the most probable speed is or how to go about calculating it please help!

d)I know that the rms speed = sqrt(3RT/M)

I'm not too good at math ( if you didn't already realize by now) so I'm not sure how to set the equation to solve for T.

T^2 = sqrt((Vrms^2(M))/3RT)

Any help is much appreciated. Thanks in advance.
 
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zferic28 said:
A physics student measures molecular speeds in a laboratory apparatus and concludes that the distribution of speeds is such that:
10% have a speed of 200 m/s
10% gave a speed of 250m/s
15% have a speed of 500m/s
30% have a speed of 650m/s
20% have a speed of 900m/s
15% have a speed of 1300 m/s

Calculate
a) the average speed
b) the rms speed
c)the most probable speed
Assuming that the apparatus contains and ideal gas with the molecular mass m = 50 x 10^-3 kg/mol, and the above distribution of speeds
d) determine the temperature of the gas in the apparatus

a) The precentages throw me off in this problem. I know that to find the average speed, I need to add up all the speeds^2 and divide by the total number of molecules.

[(1 x 200m/s) + (1 x 250m/s) + (1.5 x 500 m/s)+ (3.0 x 650 m/s) + (2 x 900m/s) + (1.5 x 1300m/s)]/10
No, not "speeds^2". This is just a standard average: add all the speeds and divide by the number. If the percentages are throwing you off, imagine that there are 100 molecules and use numbers of molecules instead:
10 have a speed of 200 m/s
10 gave a speed of 250m/s
15 have a speed of 500m/s
30 have a speed of 650m/s
20 have a speed of 900m/s
15 have a speed of 1300 m/s

b) [(1 x 200m/s)^2 + (1 x 250m/s)^2 + (1.5 x 500 m/s)^2 + (3.0 x 650 m/s)^2 + (2 x 900m/s)^2 + (1.5 x 1300m/s)^2]/10

=1.15x 10^6 m^2/s^2
Or you could assume 10 molecules instead! That's exactly what you did here.


The rms speed = sqrt(1.15x 10^6 m^2/s^2)

c) I really don't know what the most probable speed is or how to go about calculating it please help!
I'm not clear on what "most probable speed" means either- I suspect they are asking which speed the greatest number of molecules have. You don't have to "calculate" that- just look at your percentage table. What speed do the greatest percentage of molecules have?

d)I know that the rms speed = sqrt(3RT/M)

I'm not too good at math ( if you didn't already realize by now) so I'm not sure how to set the equation to solve for T.

T^2 = sqrt((Vrms^2(M))/3RT)
No, not T2.
First get rid of the square root by squareing both sides:
(rms speed)2= 3RT/M.
Now isolate T by multiplying both sides of the equation by M and dividing both sides by 3R:
T= M(rms speed)2/3R.

Any help is much appreciated. Thanks in advance.
 

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