Need to Find OCV for H2O2 Fuel Cell

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SUMMARY

The open cell voltage (OCV) for an H2/O2 fuel cell operating at 1 atm and 100°C can be calculated using the Nernst equation. The equation is E = Eo + (RT/nF) * ln[(PH2 * PO2^1/2) / PH2O], where Eo is 1.17V, R is 8.314 J/mol-K, T is 373K, n is 2, and F is 96486 C/e-. The partial pressures for hydrogen (PH2), oxygen (PO2), and water (PH2O) must be defined accurately, with water's activity set to 1. The ambiguity in the operating conditions requires clarification on the partial pressures of the gases involved.

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Homework Statement



Calculate the open cell voltage for an H2/O2 fuel cell operating at P=1atm and T = 100°C


Homework Equations



Nernst Eq: Eo+(RT/nF)*ln[(aH2)*(aO2^1/2)/(aH2O)]

The Attempt at a Solution



E=1.17V+((8.314J/mol-K)*(373K))/((2e-)*(96486C/e-))*ln[(PH2*PO2^1/2)/PH2O]



I'm not sure what the partial pressures should be such as: PH2, PO2^1/2, and PH2O.

Any help would be MUCH appreciated. Thanks:smile:
 
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Chances are I need a coffee and I am missing something obvious. If so, there are already two of us.

Activity of water is just 1. But unless there is some convention in describing fuel cells that I have no idea about, I don't see what "operating at P=1atm" is intended to mean. Perhaps it is hydrogen at 1 atm and atmospheric oxygen (so at 0.21 atm?). But if so, wording is ambiguous.
 
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