Basically, yes, a
net force causes an acceleration. This is Newton's second law, (it it's best known form, F = m a), which you've probably heard about. Suppose I push against a block of 1kg with a force of 3N. Then the block will accelerate at 3 m/s^2 (Newton's law). It will keep on doing this, as long as I push. That is: the velocity of the block, after a time
t, will be
v = 3t. As soon as I stop pushing, the force stops - the left hand side
F vanishes. Therefore, also the acceleration stops, and the block will continue to slide eternally, with speed
v = 3t0, where
t0 is the time I stopped pushing.
Now let's add in friction. When I push with a force of 3N, but there is friction, the
net force will be smaller than 3N (if I gradually turn up the force, instead of just switch it on, the net force will in fact be 0 until I push hard enough to overcome the static friction; in this case of an object at rest). Similarly, when I stop pushing the moving block, the net force will not be zero: there will still be a contribution from the friction. This net force is now in the
opposite direction though (it works against the direction of movement) so, mathematically, the force is
negative. Then so is the acceleration, in other words: the block decelerates. Finally, it will come to a stop (the frictional force decreases with the velocity, luckily - if it we're constant, the block would slow to a stop and then continue to accelerate in the other direction

).
So note the word
net in the first line. You can also see it by considering gravity. If I drop an object in free fall, it accelerates with
g (which is about 10 m/s^2). Earth exerts a force of
m g on the object. By hanging the object from a force meter, you could actually
measure the force and
determine g from it. Of course, if the object lies on a table, gravity also acts. But now the table also exerts a force (the normal force), which is exactly equal and opposite, hence the net force is zero and there is no acceleration. If you put the object on a slope, the normal force also acts, but (as the name suggests) it acts normal to the surface. Therefore, not the entire force, but just a component of it, cancels the gravitational force -- hence the object will accelerate downwards (of course, the horizontal component will cause it to accelerate sidewards as well -- in other words: the object will slide down the slope).