Normalization of the infinite square well.

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Discussion Overview

The discussion revolves around the normalization of the wave function in the context of the infinite square well in quantum mechanics. Participants explore the mathematical derivation of the normalization condition and the implications of boundary conditions on the wave function.

Discussion Character

  • Technical explanation
  • Mathematical reasoning
  • Homework-related

Main Points Raised

  • One participant expresses difficulty in completing the normalization integral for the infinite square well, referencing a textbook result that states |A|^2 = 2/a.
  • Another participant provides an alternative equation derived from Wolfram Alpha, suggesting that the normalization condition involves additional terms related to k.
  • A participant identifies that k is restricted to integer values due to boundary conditions, specifically k = nπ/a, where n is a positive integer.
  • It is noted that the term sin(2ak) becomes zero for integer values of n, simplifying the normalization expression to a/2.

Areas of Agreement / Disagreement

Participants appear to agree on the restriction of k to integer values, but there is no consensus on the initial normalization integral's evaluation, as one participant challenges the textbook result.

Contextual Notes

The discussion includes unresolved mathematical steps regarding the normalization integral and the dependence on the specific values of k, which are contingent on the boundary conditions of the infinite square well.

Jdraper
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I have been going through my textbook deriving equations in preparation for my test on QM tomorrow. I noticed in the infinite square well that i was unable to complete the normalization.

My textbook, Griffiths reads :

(integral from 0 to a) ∫|A|^2 * (sin(kx))^2 =|A|^2 * (a/2) =1 Therefore, |A|^2 = 2/a

When i do this integral i do not get this result, furthermore when i put this integral into wolfram alpha i get this result:

http://www.wolframalpha.com/input/?i=integrate+sin^2(kx)+dx+from+0+to+a

Which is also not the required result.

It's probably something stupid but help would be appreciated none the less,

Thanks in advance, John.
 
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Using the result from Wolfram Alpha, your equation becomes
$$|A|^2 \left( \frac{a}{2} - \frac{\sin(2ak)}{4k} \right) = 1$$
Recall that k is restricted to certain values because of the boundary conditions. What are those values?
 
I derived the wave equation to be:

[itex]\Psi[/itex](x) = Asin(kx), So this means k takes integer values of n?

So k's values are restricted to (n*pi/a) where n=1,2,3

Just as i was writing that out i understood, k can only take integer values so sin(2kx) will always equal 0 meaning the expression is just a/2.

Thanks a bunch :)
 
Right, ##\sin(ka) = \sin(2n\pi)## which is always zero for integer n. It's nice when "extra" terms in an equation disappear like that. :smile:
 

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