(Baby QM) Analytic Solution to the Infinite Square Well Problem

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SUMMARY

The discussion revolves around the analytical solution to the 1-D time-independent Schrödinger's equation for the infinite square well problem, where the potential is infinite at the boundaries and zero elsewhere. Participants highlight the need to normalize the wavefunction, specifically addressing the probability density function which may require a constant multiplier for proper normalization. A suggested approach involves using a nonlinear curve fitting method to determine the correct multiplier, utilizing the function P(x) = C sin²(2πx) and software tools like Origin Pro or Grace for analysis.

PREREQUISITES
  • Understanding of the 1-D time-independent Schrödinger's equation
  • Familiarity with wavefunctions and probability density functions
  • Knowledge of normalization techniques in quantum mechanics
  • Experience with nonlinear curve fitting methods
NEXT STEPS
  • Research the analytical solution for the infinite square well problem
  • Learn how to normalize wavefunctions in quantum mechanics
  • Explore nonlinear curve fitting techniques using Origin Pro
  • Investigate the use of Grace for data analysis and fitting
USEFUL FOR

Students and researchers in quantum mechanics, physicists working on wavefunction analysis, and anyone interested in numerical methods for solving Schrödinger's equation.

obstinatus
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Hi,

I think I'm having a bit of a brain fart...I'm messing with this numerical code trying to understand the 1-D time-independent Schrödinger's equation infinite square well problem (V(x) infinite at the boundaries, 0 everywhere else). If normalized Phi squared is the probability of finding the particle in that location, what the heck is the analytical solution I should plot against it to see how close it is? The normalized wavefunction given by Hyperphysics is much too large. Any and all suggestions appreciated.
Infinite Square Well.png
 
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obstinatus said:
Hi,

I think I'm having a bit of a brain fart...I'm messing with this numerical code trying to understand the 1-D time-independent Schrödinger's equation infinite square well problem (V(x) infinite at the boundaries, 0 everywhere else). If normalized Phi squared is the probability of finding the particle in that location, what the heck is the analytical solution I should plot against it to see how close it is? The normalized wavefunction given by Hyperphysics is much too large. Any and all suggestions appreciated.
View attachment 260814
What do you mean their wavefunction is too large? What specific wavefunction were you looking at?
 
That probability density function looks like it has to be multiplied with a constant greater than 50 to become normalized. Then you can compare it to the exact solution.

You can also find the correct multiplier by making a nonlinear curve fit to this data with function

##P (x) = C\sin^2 (2\pi x)##

and setting ##C## as the fitting parameter. This can be done in Origin Pro or some free program like Grace.
 

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