AJ Bentley said:
My two-pennyworth.
IMO
The classical ideas of fields and the movement of charges (not specifically electrons) don't sit well in the study of electrodynamics.
I rather like the approach taken by Prof Mead of 'explaining' electricity as a quantum effect from the outset. What's more, he points out (not in so many words) that when we study physical systems, we inevitably begin with a simple situation.
Typically we would avoid friction effects (often by setting ourselves up in a separate universe for the experiment!). For that reason, he elects to only consider superconductors.
It sounds crazy but it works. Within the first chapter of his book 'collective electrodynamics' he disposes of the E field and the B field as totally unnecessary artificial constructs and just uses the scalar and vector potentials along with simple QM concepts to completely reconstruct the subject.
He doesn't destroy Maxwell's work, he simply redirects it along the lines Maxwell would have gone if he'd been aware of facts we now know.
I can't recommend it strongly enough.
Just to give you the Flavour:-
He points out that the voltage across the ends of a loop (scalar potential) and the Vector potential A around the loop together satisfy the de Broglie relationship of frequency to wavenumber. By considering charge as a wave, it's therefore possible to specify the potentials as a four-vector throughout space - they depend only on J (also a four vector with the charge density.)
E and B - you don't need - you can easily calculate a value for them at any point if you want - but it turns out that most of the time you don't need to.
I know of Carver Mead's work quite well, In fact, if you do a search on PF, I've cited his PNAS paper on his Collective Electrodynamics several times. This is because he cited superconductivity as being the clearest manifestation of QM at the macroscopic scale. His reformulation of E&M fields is actually quite interesting and refreshing.
However, his work cannot derive, for example, Ohm's law, nor can he arrive at an explanation for "resistivity" in metals. Maxwell equations can't either. This is because this is not an issue of electromagnetic field, but rather a materials property (it is why such derivations are very seldom done in E&M classes, but rather, in solid state classes). Mead was able to describe, using his picture, various phenomena of superconductivity because the charge carrier responsible for that phenomenon has long-range coherence. The supercurrent does not interact with the microscopic details of the bulk material, what David Pines termed as a state of "quantum protectorate". So in essence, dealing with just the supercurrent made it "easier".
This is not the case with ordinary metals in the normal state. The question is, how are charges transported from one location to another, resulting in what we call a "current". We know that the charge carriers undergo several interactions: (i) electron-electron interactions, (ii) electron-ion (or phonon) interactions (iii) electron-impurities interactions), etc. (refer to, say, Valla et al., PRL 83, 2085(1999)). At room temperature, in a typical metal, the electron-ion/phonon interactions dominates, resulting in the fact that a free electron trying to move, will not make it way past the mean-free path. That's it. Without any external field, any electrons moving through such a material will thermalize. This is the
origin of resistivity. One can derive from First Principles the resistivity of various materials using such a model.
This area is such a well-studied subject in condensed matter physics, because transport phenomenon is one of the most important aspects of that field. I could easily point out to the QFT approach to such a phenomenon (to answer the question from another member who wanted to know if such a thing has to be handled quantum mechanically) using what we call as the propagator, and arrive as the single-particle spectral function. Here it is even
clearer that, analogous to the random walk problem, each charge carrier WILL experience multiple interactions impeding its motion. It is why this is a many-body physics problem. It is why the "electron" that we detect in a material does not have the same "mass" as the bare material. In heavy fermionic system, the charge carrier can have a mass more than 200 times the bare mass!
In all of these, there is a clear cause-and-effect, especially in how one gets Ohm's Law, how charges move through a material, etc.
Zz.