Orbital Diagrams and Electron Configuration Notations

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SUMMARY

The discussion centers on understanding electron configuration notations, specifically the notation "1s2" and "[Xe]6s1," which represents the electron arrangement in atoms like cesium. Key concepts include principal quantum numbers, angular momentum quantum numbers, and the significance of shorthand notations like "[Xe]." The conversation highlights that each electron is defined by four quantum numbers, and exceptions exist in the filling order of electrons in transition metals and certain elements. Resources such as Wikipedia and visual aids for electron configurations are recommended for further exploration.

PREREQUISITES
  • Understanding of quantum numbers (n, l, m sub l, m sub s)
  • Familiarity with electron configuration notation
  • Knowledge of periodic table structure
  • Basic concepts of atomic structure and electron shells
NEXT STEPS
  • Research "Quantum Numbers and Their Significance" for a deeper understanding of electron behavior.
  • Explore "Electron Configuration Exceptions in Transition Metals" to learn about unique filling patterns.
  • Study "Periodic Table Trends" to understand how electron configurations relate to element properties.
  • Utilize "Visual Tools for Electron Configurations" to practice writing configurations using periodic tables.
USEFUL FOR

Chemistry students, educators, and anyone interested in atomic structure and electron configurations will benefit from this discussion.

Mk
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I used to understand this -- a few years ago -- but it has completely slipped my mind. What is going on with al this 1s2 and Like Cs[Xe]6s1?

Thanks a lot,
Mk
 
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Principal quantum number, angular momentum quantum number and the number of electrons on the orbital specified by n and l. [Xe]6s1 means that you have the closed shell structure of Xenon and one electron in the n=6, l=0 state or in other words Cesium.
 
It is all a way of categorizing where the electrons are around the atom, putting them into "Shells", "SubShells", and "Orbitals".

http://en.wikipedia.org/wiki/Electron_configuration

Every electron around an atom has 4 quantum numbers, n (the principle quantum number), l (for angular momentum), m sub l (for its atomic orbital), and m sub s (the spin, either + or - 1/2).
No two electrons can have the exact same 4 quantium numbers.

The [Xe] is a shorthand notation, meaning that the electron configuration is the same as Xenon's up to that point, and then it contunues with a 6s1, to make it have an electron configuration of Cessium
 
Thank you very much for the replies, how can you write the electron configuration notation using only a periodic table?
 
This site has a nice visual for this.

http://www.matter-antimatter.com/electronic_configurations.htm
 
Last edited by a moderator:
Mk said:
Thank you very much for the replies, how can you write the electron configuration notation using only a periodic table?

Usually you don't. Not entirely correctly, that is. There are some exceptions from the "normal" behavior of shell filling with electrons. Vanadium, copper, zinc, silver, paladium, hydrargirum...and a lot among the lantanoids & actinoids.

Daniel.
 
If you want an explanation for what dexitroby( Sorry for misspelling) said I started a thread about the stability of electron orbitals, in atoms, moloceuls, and solids. Towards the end Gukul( Sorry potential misspelling) explained why transition metals fill up differently. The thread is towards the bottom and titled 'Stability of a full valence shell' or something like that. Hopefully this will help a little bit. I am sorry that I was too stupid to know how to create a link.
-Scott
 

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