Phase change or not: oil in the refrigerator

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SUMMARY

The discussion centers on the phase change of cooking oil when stored in a refrigerator. It is established that cooking oil transitions from a liquid to a semi-solid state as temperatures drop below a specific threshold, indicating a phase transition. Unlike oil, honey undergoes crystallization due to sugar separation, which is a different process. The conversation highlights that most cooking oils are mixtures of lipids, leading to a gradual transition rather than a sharp change from liquid to solid.

PREREQUISITES
  • Understanding of phase transitions in materials
  • Knowledge of lipid mixtures and their properties
  • Familiarity with crystallization processes
  • Basic thermodynamics related to temperature effects on substances
NEXT STEPS
  • Research the phase transition temperatures of various cooking oils
  • Explore the chemical composition of different lipid mixtures
  • Investigate the crystallization process in honey and other sugar solutions
  • Study the thermodynamic principles governing phase changes in mixtures
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Food scientists, culinary professionals, and anyone interested in the physical properties of cooking oils and their behavior under varying temperature conditions.

Spinnor
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Cooked some french fries last night using oil saved in the refrigerator. The oil appears to have undergone a phase change, after some time in the refrigerator instead of being a yellowish transparent liquid it was a semi-solid soft whitish non-transparent stuff when I took it out of the refrigerator to use it to cook. This morning it was still a yellowish transparent liquid. When the oil changes from a transparent liquid to a semi-solid soft whitish non-transparent stuff that technically a phase change? Over time honey also seems to undergo a similar "phase change".

Thanks.
 
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Yes, oil will become solid as it goes below a certain temperature. It is the usual phase transition from liquid to solid.

What happens with honey is quite different. It is much more a mixture, and what is observed is the crystallisation of the sugar separating out of the mixture.
 
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Most cooking oils are mixtures of lipids so often there isn't a sharp transition from liquid to solid. As the temperature is lowered parts of the mixture will freeze first, producing a cloudy, viscous liquid/solid mixture. Below a certain temperature it will be completely frozen.
 
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