Plane Waves in TDSE: Group & Phase Velocity

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SUMMARY

Plane waves are solutions to the Time-Dependent Schrödinger Equation (TDSE) only in regions where the potential V is constant. When V=0, the plane wave solution satisfies the TDSE, demonstrating that group velocity equals the particle velocity (v) while phase velocity equals v/2. The distinction between group and phase velocity highlights that group velocity corresponds to the effective speed of wave packets and information propagation, whereas phase velocity does not directly relate to energy eigenstates in non-constant potentials.

PREREQUISITES
  • Understanding of the Time-Dependent Schrödinger Equation (TDSE)
  • Knowledge of wave mechanics and wave packet propagation
  • Familiarity with concepts of group velocity and phase velocity
  • Basic principles of quantum mechanics, particularly regarding potential energy
NEXT STEPS
  • Study the implications of constant versus non-constant potentials in quantum mechanics
  • Explore the derivation of group and phase velocities in wave mechanics
  • Investigate boundary conditions in quantum systems and their effects on wave functions
  • Learn about energy eigenstates and their relationship to momentum in varying potentials
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Students and professionals in quantum mechanics, physicists analyzing wave functions, and educators teaching concepts of wave behavior in quantum systems.

sachi
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We are asked to substitute a plane wave solution into the TDSE for V=0 and show that it satisfies the TDSE (this is straightforward). Does this mean the plane waves are only solutions to the TDSE if V=0, or do they have other significance?

Also we show that the group velocity = v (the particle velocity) and that the phase velocity =v/2. The calculations are straighforward but the interpretation is difficult. I can see why the group velocity (the effective speed of the wave packet and the speed at which information is propogated) = v, but I can't see why the phase velocity = v/2.
Thanks
 
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Yes, in general plane waves are only solutions of the Schrödinger equation in regions where the potential is constant. The further imposition of boundary conditions when the potential is a series of steps generally restricts these states further (unlike in the free space case where the potential is the same constant everywhere). You can understand this quite physically as follows. The plane waves are states of definite momenta, but you know that in the presence of a non-constant potential, the momentum will change, therefore these states can't have definite energy (they can't be energy eigenstates) when the potential varies with position.

The point about the phase velocity versus group velocity bit is simply that the group velocity is what corresponds most directly with what you are familiar with from classical mechanics.
 

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