Phase velocity and frequency of a matter wave

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SUMMARY

The discussion centers on the relationships governing matter waves, specifically the equations λ = h / p and E = h f, where E = mc². It establishes that the phase velocity vph = c² / v, with v being the group velocity, leads to infinite wavelength and phase velocity when considering a stationary particle as v approaches zero. The conversation also clarifies the distinction between non-relativistic and relativistic quantum mechanics, emphasizing that the inclusion of rest mass energy alters the frequency but not the de Broglie wavelength, thus maintaining consistent physics across models.

PREREQUISITES
  • Understanding of quantum mechanics principles, specifically non-relativistic and relativistic QM.
  • Familiarity with the de Broglie hypothesis and matter wave theory.
  • Knowledge of the equations E = mc² and E² = p²c² + m²c⁴.
  • Basic grasp of wave-particle duality and its implications in quantum physics.
NEXT STEPS
  • Study the implications of the de Broglie wavelength in quantum mechanics.
  • Explore the differences between non-relativistic and relativistic quantum mechanics.
  • Learn about electron diffraction and its relation to wave-particle duality.
  • Investigate the role of rest mass energy in quantum field theory.
USEFUL FOR

Physicists, quantum mechanics students, and researchers interested in the foundational concepts of matter waves and their implications in both non-relativistic and relativistic frameworks.

  • #31
Philip Koeck said:
Are the equations on Wikipedia right?
Post 25 in this thread suggests a different expression connecting E and f.
I think you are confused going between non-relativistic "energy", which is all kinetic, and relativistic "energy", which includes mass-energy. These are not the same quantities. One is not a low-speed approximation of the other.
 
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  • #32
PeroK said:
I think you are confused going between non-relativistic "energy", which is all kinetic, and relativistic "energy", which includes mass-energy. These are not the same quantities. One is not a low-speed approximation of the other.
Yes, I know.
According to the Wikipedia text E = h f, where E is the total relativistic energy, including the rest mass term.
According to post 24 the relationship is E - m0c2= h f, if I'm not mistaken.
I'm simply wondering which of the two is correct for relativistic velocities.
 
  • #33
Philip Koeck said:
Yes, I know.
According to the Wikipedia text E = h f, where E is the total relativistic energy, including the rest mass term.
This must be correct.
Philip Koeck said:
According to post 24 the relationship is E - m0c2= h f, if I'm not mistaken.
I don't see that in post #24.
Philip Koeck said:
I'm simply wondering which of the two is correct for relativistic velocities.
It's the total relativistic energy. It must be.
 
  • #34
PeroK said:
I don't see that in post #24.
In post 24 it says vΦ= ω/k, and then ω is replaced by E - mc2, as I read it. (The h cancels or is set to 1, c is set to 1).
 
  • #35
Particles are not waves and you should not confuse their equations - phase velocity isn't so meaningful for particles.
 
  • #36
Philip Koeck said:
In post 24 it says vΦ= ω/k, and then ω is replaced by E - mc2, as I read it. (The h cancels or is set to 1, c is set to 1).
Okay, I'll let @ergospherical explain that!
 
  • #37
ergospherical said:
Particles are not waves and you should not confuse their equations - phase velocity isn't so meaningful for particles.
Yes, I'm getting that impression.
Just to make sure, from your expression for vΦ, what do you get when v approaches c and does vΦ ever exceed c (as the Wikipedia text claims)?
 
  • #38
Philip Koeck said:
At least to me that leads to a problem.
If it's enough of a problem that its effect on your answer matters, then obviously you are dealing with a case where the non-relativistic approximation won't work for you and you need to use the relativistic equations.
 
  • #39
Philip Koeck said:
I'm simply wondering which of the two is correct for relativistic velocities.
In relativity rest mass is part of the total energy. So it has to be included.
 
  • #40
ergospherical said:
In the relativistic region the phase velocity is ##v_{\phi} = \omega/k = (E-m)/p##, i.e.\begin{align*}
v_{\phi} = \frac{\gamma - 1}{\gamma v}
\end{align*}For small ##v## expand ##\gamma = (1-v^2)^{-1/2} \sim 1 + v^2/2## (and similarly ##1/\gamma \sim 1-v^2/2##) to get\begin{align*}
v_{\phi} &\sim \frac{(v^2/2)}{v}(1-v^2/2) \sim \frac{v}{2}
\end{align*}omitting terms ##O(v^3)##.
Could you share a source for the relationships you use in the first line?
Especially E -mc2= ħω, if that is what you are using.
Is there a book that says that?
 
  • #41
Philip Koeck said:
When I write m I mean the relativistic mass, not the rest mass.
Don't do that. It kinda sort of works if you're just doing a semester or so of special relativity with classical objects (but even that is discouraged these days - why start with something that has to be unlearned to move beyond that first semester or so?) but fails dismally as soon as you start thinking quantum mechanics.

With QM in the picture: If relativity doesn't matter there is no relativistic mass, if it does matter you have to use the relativistic ##E^2=(mc^2)^2+(pc)^2## instead of anything involvng relativistic mass.
 
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  • #42
A (hopefully) final question on this:
Clearly the wavelength of a matter wave can be measured directly in a diffraction experiment so the relation p = h k can be tested experimentally by sending particles of known p through a grating.

Is there a similar way to test E = h f?
Can f be measured directly without inferring it from E?

Or, alternatively, is there a way to measure the phase velocity of a matter wave?
 

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