Pressure of gasoline in a closed container

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SUMMARY

The discussion centers on calculating the pressure of gasoline in a closed container using the ideal gas law, specifically the equation p = nRT/V. The key challenge presented is determining the amount of gasoline that evaporates to reach a critical pressure where the evaporation rate equals the dissolving rate. It is established that saturated vapor pressure tables for gasoline or its typical components at 25°C are essential for accurate calculations, given that gasoline is a mixture of hydrocarbons with no definite composition.

PREREQUISITES
  • Understanding of the ideal gas law (p = nRT/V)
  • Knowledge of saturated vapor pressure concepts
  • Familiarity with the properties of hydrocarbons
  • Basic thermodynamics principles
NEXT STEPS
  • Research saturated vapor pressure tables for gasoline and its components
  • Study the relationship between temperature and vapor pressure in hydrocarbons
  • Explore the concept of dynamic equilibrium in evaporation and condensation
  • Learn about the impact of temperature on the evaporation rate of liquids
USEFUL FOR

Chemical engineers, thermodynamics students, and anyone involved in the study of fluid dynamics and vapor pressure in hydrocarbon mixtures.

barryj
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Homework Statement
A small amount of gasoline is placed in a 1 liter container along with the normal atmospheric pressure of 760 torr at 25C. Much but not all of the gasoline evaporates creating an increased pressure inside the container. At equilibrium, what will be the total pressure in the container?
Relevant Equations
pv = nrt P total = P atmosphere + P gasoline
If I knew how much of the gasoline evaporated, then I could use p = nRT/V to fine the partial pressure of the gasoline and add it to the pressure of the atmosphere. So my question is, How do I find how much of the gasoline will evaporate. I would think that the gasoline would evaporate until it reached some critical pressure at which time the evaporation rate would equal the disolving rate. but how do I find this? Is there some law I do not know about?
 
Physics news on Phys.org
Gasoline is a mixture of hydrocarbons, and it doesn't have a definite composition - so it is not like there is an unambiguous answer to the question.

There is not much you can do without tables of saturated vapor pressure of gasoline (or it most typical components) at 25°C.
 

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