Probability of a state given the partition function

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Homework Help Overview

The discussion revolves around the application of the partition function in statistical mechanics, specifically regarding the probability of a system being in a state with a given energy within a continuous energy distribution context.

Discussion Character

  • Exploratory, Conceptual clarification, Mathematical reasoning

Approaches and Questions Raised

  • Participants explore the relationship between the partition function and the probability of states, questioning the validity of using a simple exponential form for continuous energy distributions. There is a discussion on the need for integration over small intervals and the role of phase-space distribution functions.

Discussion Status

The conversation is active, with participants offering insights into the formulation of the probability in terms of phase-space and energy. Some guidance has been provided regarding the evaluation of integrals and the importance of understanding the phase-space distribution for ideal gases.

Contextual Notes

There is an indication that the original poster may be grappling with the implications of continuous energy distributions and the necessary mathematical treatment, including integration and the specifics of the phase-space variable.

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Homework Statement
Given the partition function of an ideal monoatomic gas, what is the probability that its energy is some ##cU##, where ##U## is the average energy of the ensemble
Relevant Equations
##Z = \frac{1}{N!} \left( \frac{2\pi m k_B T}{h^2} \right)^{3N/2} V^N##
If my partition function is for a continuous distribution of energy, can I simply say that the probability of my ensemble being in a state with energy ##cU## is ##e^{-\beta cU} /Z##? I believe that isn't right as my energy distribution is continuous, and I need to be integrating over small intervals.
 
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First think about the phase-space distribution function in terms of energy rather than momentum!
 
So,
$$p(E) = \int \delta(E-cU) \frac{e^{-\beta E(\Gamma)}}{Z} d\Gamma$$
where ##\Gamma## is the phase-space.
However, how do I simplify something like this?
 
Last edited:
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Well, just get ##E(\Gamma)##.
 
How do you mean?
 
Well, you should know, how the phase-space distribution function for an ideal gas looks. Then you can get the distribution function of energy by evaluating the integral you've written down.
 

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