We are given $$a^5+b^3 \le a^2+b^2$$ and wish to show if that then $$a(a+b) \le 2$$
add ##a^2 + ab## to both sides
$$a^2 + ab + a^5+b^3 \le a^2 + ab + a^2+b^2$$ then move some terms over
$$a(a + b) \le 2a^2 + ab +b^2 - a^5 - b^3$$ the expression on the RHS is some function
$$f(a,b) = 2a^2 + ab +b^2 - a^5 - b^3$$ which we can find the maximum of. Taking partials we get
$$\frac{\partial f(a,b)}{\partial a} = 4a + b -5a^4 = 0$$ and
$$\frac{\partial f(a,b)}{\partial b} = a +2b -3b^2 = 0$$we get
$$ a = 3b^2 -2b$$ and $$b = 5a^4 -4a$$ substituting we get this beast
$$75a^7 -120a^4 -10a^3 + 48a +7 = 0$$ which has real positive solutions ##a=1## and ##a≈0.90173## the latter gives ##b≈-0.30812## which is not allowed so we have ##a=1## and therefore ##b=1##
this gives $$f(1,1) = 2a^2 + ab +b^2 - a^5 - b^3 = 2 + 1 + 1 - 1 -1 = 2$$ thus
$$a(a+b) \le 2$$ given the original constraint.
Mathcad 3D
https://www.math3d.org/TRHrXnwZS
[\SPOILER]