Radial distribution probability

Click For Summary

Homework Help Overview

The discussion revolves around the calculation of the probability of finding an electron within a sphere of a certain radius using the radial distribution probability function. Participants are exploring the integration of this function with respect to the radius.

Discussion Character

  • Conceptual clarification, Mathematical reasoning

Approaches and Questions Raised

  • The original poster questions whether to integrate the radial distribution probability function from 0 to infinity or to use the product of the function times dr for probability calculation. Some participants provide clarification on the relationship between the radial distribution function and the probability of finding a particle in a spherical shell.

Discussion Status

Participants are actively engaging with the original poster's question, with one providing a formula that outlines the probability calculation. There is acknowledgment of the complexity introduced by additional variables in the wavefunction, suggesting a productive direction in the discussion.

Contextual Notes

The original poster has not provided the full homework problem, indicating a desire to work through it independently while seeking clarification on a specific aspect of the probability calculation.

hellomister
Messages
29
Reaction score
0

Homework Statement


When I'm trying to find the probability of finding an electron within a sphere of a certain radius, do i integrate the radial distribution probability function with respect to r from 0 to infinity? My book says the product of the radial distribution function times dr would give the probability, but I always thought you had to integrate it.


Homework Equations


n/a just looking for a simple answer to my question... i didnt show the homework problem cos i want to do it myself i just want this question answered.

The Attempt at a Solution


I've attempted the problem, i just integrated and I want to know if you should integrate.
 
Physics news on Phys.org
The probability of finding the particle in a shell of thickness dr having radius r is

dP=|\psi|^2\:4\pi r^2dr

The probability of finding the particle anywhere within a sphere of radius R is

P=\int^R_0 |\psi|^2\:4\pi r^2dr

Does this help?
 
yes! helps a ton! Thank you.
 
Notice that 4\pi r^{2} is the area of the surface of a sphere. This factor looks like that because you only have radial distribution, independent of azimuthal direction,
while if your wavefunction looks like \psi(r,\theta,\phi) things will get a little more complicated, and will involve additional integrations.
 

Similar threads

  • · Replies 21 ·
Replies
21
Views
2K
  • · Replies 12 ·
Replies
12
Views
3K
  • · Replies 5 ·
Replies
5
Views
2K
  • · Replies 1 ·
Replies
1
Views
2K
  • · Replies 1 ·
Replies
1
Views
2K
  • · Replies 1 ·
Replies
1
Views
4K
  • · Replies 2 ·
Replies
2
Views
4K
  • · Replies 2 ·
Replies
2
Views
2K
Replies
5
Views
2K
  • · Replies 8 ·
Replies
8
Views
2K