Rayleigh Scattering and linear polarization

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Rayleigh scattering explains how sunlight interacts with the atmosphere, leading to the scattering of unpolarized light. When sunlight hits atmospheric molecules, the oscillating electrons create scattered light that is predominantly horizontally polarized. This polarization occurs because the scattering process aligns the oscillation directions of the electrons in the molecules. The unscattered light remains unpolarized as it does not interact with the molecules in the same way. Understanding these principles clarifies why scattered sunlight appears polarized.
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Hello,

I am having a bit of trouble understanding the concept of Rayleigh scattering as it relates to light from the sun. My book states that unpolarized light will hit the atmosphere, and the scattered light will be mainly horizontally polarized, while the unscattered light remains unpolarized. Why is this? I understand that the light will scatter because of oscillating electrons in electric dipoles, but I don't see why that would result in sunlight being horizontally polarized. Do all molecules in the atmosphere have similar oscillation directions?

Thanks!
 
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