Reif Ch7, Decomposition of partition function

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SUMMARY

The discussion focuses on the decomposition of the partition function for a system A comprised of two weakly interacting parts, A' and A''. The energy of the combined system is additive, expressed as E_{rs} = E^{'}_{r} + E^{''}_{s}. The partition function Z is derived as Z = Z'Z'', where Z' and Z'' are the partition functions of the individual components. The key question raised is the mathematical justification for transforming the sum of products into the product of sums, specifically how the expression $$\sum_r \big[\sum_s e^{-\beta E_r}e^{-\beta E_s}\big]$$ can be rewritten as $$\sum_r \big[ e^{-\beta E_r}\sum_s e^{-\beta E_s}\big].

PREREQUISITES
  • Understanding of statistical mechanics concepts, particularly partition functions.
  • Familiarity with the mathematical properties of summation and exponentiation.
  • Knowledge of weakly interacting systems in thermodynamics.
  • Basic proficiency in manipulating mathematical expressions involving sums and products.
NEXT STEPS
  • Study the derivation of partition functions in statistical mechanics.
  • Explore the properties of exponential functions in the context of summation.
  • Learn about weakly interacting systems and their implications in thermodynamics.
  • Investigate the mathematical techniques for transforming sums and products in advanced calculus.
USEFUL FOR

This discussion is beneficial for students and researchers in physics, particularly those studying statistical mechanics, thermodynamics, and mathematical methods in physics. It is also relevant for anyone interested in the mathematical foundations of partition functions.

msaleh87
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Homework Statement



For a system A consists of two parts A' and A'' which interact only weakly with each other, if the states of A' and A'' are labeled respectively by r and s, then a state of A can be specified by the pair of numbers r,s and its corresponding energy [itex]E_{rs}[/itex] is simply additive, i.e.,
[itex]E_{rs}[/itex] = [itex]E^{'}_{r}[/itex] + [itex]E^{''}_{s}[/itex]

The partition function Z for the total system A is a sum over all states labeled by rs, i.e.,


Z=[itex]\sum_{r,s}e^{-\beta(E^{'}_{r}+E^{''}_{s})}[/itex] = [itex]\sum_{r,s}e^{-\beta E^{'}_{r}} \ e^{E^{''}_{s}}[/itex] = ([itex]\sum_{r}e^{-\beta E^{'}_{r}}[/itex])([itex]\sum_{r}e^{-\beta E^{''}_{s}}[/itex]) = [itex]Z^{'}Z^{''}[/itex]


My question is: how the sum of product [itex]\sum ()()[/itex] is converted to product of sum ([itex]\sum[/itex])([itex]\sum[/itex]), they are not generally equal

Thanks
 
Last edited:
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Do you understand why you can do this?
$$\sum_r \big[\sum_s e^{-\beta E_r}e^{-\beta E_s}\big] = \sum_r \big[ e^{-\beta E_r}\sum_s e^{-\beta E_s}\big] $$
 

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