Relationship between work, internal energy and enthelpy.

In summary, the conversation discusses the relationship between work, enthalpy, and internal energy in a thermodynamics class. It is debated whether work done by a system is equal to the change in internal energy or enthalpy, with a specific example given for a steam turbine. It is concluded that enthalpy includes both internal energy and "flow work" and therefore would be used in the calculation for the turbine. It is also mentioned that the work done by a system depends on the situation and can be calculated using different formulas.
  • #1
zzinfinity
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Hi,
I'm taking a thermodynamics class and I'm stuck on how work relates to enthalpy and internal energy.
Does work done by a system equal change in internal energy, change in enthalpy or does it depend on the situation?

The question I'm stuck on asks for the work produced by a steam turbine and gives initial and final properties for the steam. I feel like the work produced by the turbine is just equal to the ΔU for the steam, but I could also see an argument for using ΔH. Any thoughts would be appreciated.
 
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  • #2
Mass flowing across a control surface brings energy (neglecting potential and kinetic energy changes):

u + P [itex]\nu[/itex]

where,

u = fluid specific internal energy
P = fluid static pressure
[itex]\nu[/itex] = fluid specific volume

But this is the definition of enthalpy:

h = u + P [itex]\nu[/itex]

So enthalpy includes the internal energy and the "flow work" term P [itex]\nu[/itex].

So for your turbine you will use Δh as you mentioned.
 
  • #3
The work done by a system depends on the situation.
The general formulas are:
dU=dQ+dW
dU=TdS-PdV
dH=TdS+VdP

I think you would use ΔH=ΔQ for a quasi-static, constant-pressure process.
And you would use ΔU=-ΔW for an adiabatic process.

I believe both processes apply in a steam turbine cycle.
 

FAQ: Relationship between work, internal energy and enthelpy.

1. What is the relationship between work and internal energy?

The relationship between work and internal energy is that work is a transfer of energy from one system to another, while internal energy is the total energy contained within a system. When work is done on a system, it can increase the internal energy of that system.

2. How does internal energy affect enthalpy?

Internal energy and enthalpy are directly related, as enthalpy is defined as the sum of a system's internal energy and the product of its pressure and volume. Therefore, any changes in the internal energy of a system will also affect its enthalpy.

3. Can work be used to change the enthalpy of a system?

Yes, work can be used to change the enthalpy of a system. By doing work on a system, the internal energy can be increased or decreased, which in turn changes the enthalpy of the system.

4. How does the relationship between work, internal energy, and enthalpy affect chemical reactions?

In chemical reactions, work can be done by or on the system, which can change the internal energy and enthalpy. This can affect the overall energy of the system and determine whether the reaction is endothermic or exothermic.

5. What factors can affect the relationship between work, internal energy, and enthalpy?

The relationship between work, internal energy, and enthalpy can be affected by factors such as the amount of work done on the system, the pressure and volume of the system, and the type of chemical reactions taking place. Changes in any of these factors can alter the overall energy of the system and impact the relationship between these three variables.

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