Relationship between work, internal energy and enthelpy.

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SUMMARY

The relationship between work, internal energy, and enthalpy is crucial in thermodynamics, particularly in analyzing steam turbines. Work produced by a steam turbine is determined by the change in enthalpy (ΔH), as it accounts for both internal energy and flow work. The relevant equations include dU = dQ + dW, dU = TdS - PdV, and dH = TdS + VdP. In a quasi-static, constant-pressure process, ΔH equals ΔQ, while for an adiabatic process, ΔU equals -ΔW.

PREREQUISITES
  • Understanding of thermodynamic principles, specifically work, internal energy, and enthalpy.
  • Familiarity with the first law of thermodynamics and its equations.
  • Knowledge of steam turbine operation and thermodynamic cycles.
  • Basic grasp of fluid mechanics, particularly specific energy terms.
NEXT STEPS
  • Study the derivation and application of the first law of thermodynamics in various processes.
  • Learn about the Rankine cycle and its relevance to steam turbine efficiency.
  • Explore the concept of flow work and its implications in fluid dynamics.
  • Investigate the differences between adiabatic and isothermal processes in thermodynamic systems.
USEFUL FOR

Students in thermodynamics, engineers working with steam turbines, and professionals involved in energy systems analysis will benefit from this discussion.

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Hi,
I'm taking a thermodynamics class and I'm stuck on how work relates to enthalpy and internal energy.
Does work done by a system equal change in internal energy, change in enthalpy or does it depend on the situation?

The question I'm stuck on asks for the work produced by a steam turbine and gives initial and final properties for the steam. I feel like the work produced by the turbine is just equal to the ΔU for the steam, but I could also see an argument for using ΔH. Any thoughts would be appreciated.
 
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Mass flowing across a control surface brings energy (neglecting potential and kinetic energy changes):

u + P [itex]\nu[/itex]

where,

u = fluid specific internal energy
P = fluid static pressure
[itex]\nu[/itex] = fluid specific volume

But this is the definition of enthalpy:

h = u + P [itex]\nu[/itex]

So enthalpy includes the internal energy and the "flow work" term P [itex]\nu[/itex].

So for your turbine you will use Δh as you mentioned.
 
The work done by a system depends on the situation.
The general formulas are:
dU=dQ+dW
dU=TdS-PdV
dH=TdS+VdP

I think you would use ΔH=ΔQ for a quasi-static, constant-pressure process.
And you would use ΔU=-ΔW for an adiabatic process.

I believe both processes apply in a steam turbine cycle.
 

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