Schrodinger equation and boundary conditions

Join the discussion
Ask a follow-up here, or get your own question answered by working scientists, mathematicians and engineers — people, not an autocomplete.
Real named experts · corrections over time · the nuance an AI answer skips
2 replies · 2K views
BRN
Messages
107
Reaction score
10
Hi at all,
I'm tring to solve Schrödinger equation in spherically symmetry with these bondary conditions:

##\lim_{r \rightarrow 0} u(r)\ltimes r^{l+1}##
##\lim_{r \rightarrow 0} u'(r)\ltimes (l+1)r^{l}##

For eigenvalues, the text I'm following says that I have to consider that the eigenfunctions are tending to zero at the extremes of integration, i.e. ##r = 0## and ##r = 3 * r_{nucl}##

Why I need to consider an eigenfunction=0 in r=0? I would expect it to be maximum at that point...

Some idea?

Thanks.
 
Physics news on Phys.org
BRN said:
Hi at all,
I'm tring to solve Schrödinger equation in spherically symmetry with these bondary conditions:

##\lim_{r \rightarrow 0} u(r)\ltimes r^{l+1}##
##\lim_{r \rightarrow 0} u'(r)\ltimes (l+1)r^{l}##

For eigenvalues, the text I'm following says that I have to consider that the eigenfunctions are tending to zero at the extremes of integration, i.e. ##r = 0## and ##r = 3 * r_{nucl}##

Why I need to consider an eigenfunction=0 in r=0? I would expect it to be maximum at that point...

Some idea?

Thanks.
What is the potential ##V(r)?## In general, if you change the function ##V## you can/will change the nature of the solution ##u(r)##.
 
Now, I'm using the harmonic oscillator potential:
##
\frac{1}{2}m \omega^2r^2
##

But these boundary conditions are used for Woods-Saxon potential too.