Solving for n_1 and n_2 in Hydrogen Line Spectra

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SUMMARY

This discussion focuses on solving for the initial (n_1) and final (n_2) quantum numbers in the context of Hydrogen line spectra using the Rydberg Equation. The wavelengths provided are 656.4 nm (red), 486.3 nm (turquoise), 434.2 nm (purple), and 410.3 nm (purple). The Rydberg Equation is correctly identified as 1/λ = R_H(1/n_2² - 1/n_1²), where R_H is Rydberg's constant. Participants suggest starting with n_1 = 1 and incrementing n_2 to find integer solutions, emphasizing that the visible lines correspond to the Balmer series.

PREREQUISITES
  • Understanding of the Rydberg Equation
  • Familiarity with quantum numbers in atomic physics
  • Knowledge of the Balmer series in Hydrogen spectra
  • Basic algebra skills for solving equations with two variables
NEXT STEPS
  • Research the Rydberg constant (R_H) value and its significance in spectral analysis
  • Study the Balmer series and its implications for Hydrogen's emission spectrum
  • Learn how to apply selection rules in quantum mechanics
  • Explore methods for solving systems of equations with multiple variables
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Students and educators in physics, particularly those studying atomic spectra, quantum mechanics, and anyone needing to solve problems involving the Rydberg Equation.

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I need help on this problem that asks me to solve for [tex]n_1[/tex] and [tex]n_2[/tex] (the initial and final quantum numbers).

This is the given information (the line spectra for Hydrogen):

color red known wavelength: 656.4 nm
color turquoise known wavelength: 486.3 nm
purple wavelength: 434.2 nm
purple wavelength: 410.3 nm

[tex]n_1[/tex] and [tex]n_2[/tex] are unknown for each one.

I've tried using this equation, the Rydberg Equation, to solve for [tex]n_1[/tex] and [tex]n_2[/tex]:

[tex]\frac {1}{\lambda} = (R_H)(\frac {1}{n^2_2} - \frac {1}{n^2_2})[/tex]

where [tex]\lambda[/tex] is the wavelength, [tex]n_1[/tex] and [tex]n_2[/tex] are the initial and final principal quantum numbers, with the initial one being larger than the final one. [tex]R_H[/tex] is Ryberg's constant.

I've plugged in the numbers and (for the color red) I got
[tex]\frac {1}{656.4} = \frac {R_H}{n^2_1} - \frac{R_H}{n^2_2}[/tex]

I still can't find n1 and n2. Am I using the right formula? I just couldn't understand how to solve a problem with 2 variables.
 
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Well n2 > n1, so pick n1 = 1, then solve for n2, which must be an integer.

If that doesn't work, then try n1 = 2, and solve for n2.

Alternatively, one can select n1=1, and then using n2 = 2, 3, 4, . . . solve for the wave lengths.

What value is one using for Rydberg's constant.

Try this reference - http://hyperphysics.phy-astr.gsu.edu/Hbase/hyde.html

Hint - the visible lines are in the Balmer series.
 
Also, consider the selection rules as well as the determination of the ionization energy.
 

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