Solving Nano Tio2 in Water: Challenges and Solutions

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Discussion Overview

The discussion revolves around the challenges of dispersing nano TiO2 in water for the purpose of creating nanocomposites. Participants explore the solubility and dispersion of TiO2, as well as methods to achieve stable suspensions.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested
  • Mathematical reasoning

Main Points Raised

  • One participant expresses difficulty in dissolving nano TiO2 in water, despite claims in literature suggesting it can dissolve.
  • Another participant asserts that TiO2 is insoluble in water and suggests that the literature may be incorrect or that a specific procedure is required.
  • A different viewpoint suggests that "dissolve" may be used interchangeably with "disperse," recommending the use of a dispersant to achieve a stable dispersion of the nanopowder.
  • A participant questions how to remove a solvent after dispersion, noting concerns about water evaporation and the need for a homogeneous composite.
  • It is noted that while TiO2 does not dissolve into free ions in water, stable colloidal suspensions can be achieved with small particles and appropriate dispersants. However, achieving homogeneity on the nanoscale may require additional methods such as sol-gel or polymerized complex techniques.

Areas of Agreement / Disagreement

Participants do not reach a consensus on the solubility of TiO2 in water, with some asserting it is insoluble while others suggest that dispersion is possible with the right techniques. The discussion remains unresolved regarding the best methods for achieving a homogeneous composite.

Contextual Notes

There are limitations regarding the definitions of "dissolve" and "disperse," as well as the effectiveness of different methods for achieving homogeneity in nanocomposites. The discussion also highlights the potential need for specialized literature on the subject.

dana3kil
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Hi every one .
I am trying to make nanocomposite and I need to solve nano Tio2 in water
many paper said that it will dissolve in water
but I could not .
I don not know what is the problem :cry:
 
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TiO2 is insoluble in water. If 'many paper' say it is, they are either wrong or there is some procedure which is used and you are not picking up on it.

http://en.wikipedia.org/wiki/Titanium_dioxide

This article says nanotubes of TiO2 are prepared using either a strong NaOH solution or a dilute HF solution.
 
"Dissolve" and sometimes "solve" is often used as a synonym of disperse. So if you mean that you are unable to obtain a stable dispersion of your nanopowder, you should try adding a dispersant.
 
Thank you
but in case of using a solvent how can I get rid of it . (water will evaporate )
and will dispersion give me homogeneous composite or I need to dissolve the material
 
As already said, TiO2 is insoluble in water in the sense of decomposing into free ions. However, with sufficiently small particles and appropriate dispersants you can obtain relatively stable suspensions. In the case of very small particles, i.e. nanosized ones the suspension is called colloidal solution. In order to obtain a homogeneous composite you need to obtain a homogeneous and stable suspension of your TiO2 and whatever other materials are to from the composite with the aid of a dispersant (also called defloculant sometimes). However, this approach is not very adequate for achieving homogeneity on the nanoscale since the nanoparticles easily flock together even in very well defloculated suspensions. For nanocomposites there are other methods for achieving high homogeneity such as sol-gel, polymerized complex, etc. I recommend you to go to the library and find a specialized book on ceramic materials or composites processing. Also check carefully if a synthesis procedure hasn't already been developed. There is a high probability there are publications describing it.
 

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