Specific heat capacity of calorimeter

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SUMMARY

The discussion centers on calculating the heat capacity of a calorimeter when a copper piece is placed in water. The specific heat capacities are established as 0.39 kJ/kg·°C for copper and 18.4 kJ/kg·°C for water. The heat transfer calculations yield a net heat transfer of 4.31 kJ, which is used to derive the calorimeter's heat capacity using the formula h(ΔT) = Q. The discussion emphasizes that the calorimeter's heat capacity should be calculated with respect to the water's temperature when both are in thermal equilibrium.

PREREQUISITES
  • Understanding of specific heat capacity and heat transfer principles
  • Familiarity with the first law of thermodynamics
  • Basic knowledge of calorimetry and thermal equilibrium
  • Ability to perform calculations involving mass, temperature change, and heat transfer
NEXT STEPS
  • Study the principles of calorimetry in detail
  • Learn about the first law of thermodynamics and its applications
  • Explore examples of heat transfer calculations in different systems
  • Investigate the effects of different materials on heat capacity
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This discussion is beneficial for students in physics or chemistry, educators teaching thermodynamics, and anyone interested in understanding calorimetry and heat transfer calculations.

Pouyan
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I've got a problem:
A piece of copper with mass m1 = 800 g and temperature t1 = 80 ° C is placed in a container with good thermal insulation. The vessel initially contains water with mass m2 = 500 g temperature t2 = 20 C. What is the calorimeter (including thermo meter) heat capacity if the end temperature is tf = 26 C?!

The solution is:

the specific heat capasity for copper: 0:39 kJ / kg.C
and for water: 18.4 kJ / kg.C
dQ copper = m1 * CCU * (t1-t0) = 16.85 kJ

dQ water = m2* CH20 * (t0-t1) = 12:54 kJ

According to the first law of thermodynamics, the amount of heat transferred to the calorimeter and thermometer:

dQ = dQ copper - dQ water = 4.31 kJ

But how can I find the heat capacity of the calorimeter?
I see a solution that I should do this: 4.31 kJ / (26-20) C

but why water in this case?! should I always find the specific heat capacity of the calorimeter or the thermometer with respect to the minimum tempraturen?!
 
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Heat capacity(not specific heat) is nothing but mass times specific heat. If h be the heat capacity of the calorimeter including thermometer and your calculation is correct, then
##h(26-20) = 4.31##
 
Korak Biswas said:
Heat capacity(not specific heat) is nothing but mass times specific heat. If h be the heat capacity of the calorimeter including thermometer and your calculation is correct, then
##h(26-20) = 4.31##

Should I think:

Q los = Q gain

and Q gain = Q water + Q calorimeter ?!
 
Pouyan said:
Should I think:

Q los = Q gain

and Q gain = Q water + Q calorimeter ?!

Heat emitted by piece of copper = heat absorbed by water + heat absorbed by calorimeter including thermometer.
It follows from the conservation of energy.
 
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Korak Biswas said:
Heat emitted by piece of copper = heat absorbed by water + heat absorbed by calorimeter including thermometer.
It follows from the conservation of energy.
So we reduce 26 with the temprature of water for calorimeter ...is this always like this? If water is in the system should we find always the heat capacity of calorimeter with respect to water temprature ? What if water is not involved ?!I ask for an apology that I asked like this but I am a beginner...
thanks !
 
In a problem like this, it is assumed that the water and the calorimeter are initially in thermal equilibrium with each other before the copper is added. So, you can assume the calorimeter and the water have the same initial temperature (20 oC in this case.)

If there is no water so that the copper is placed in an empty calorimeter, then you would need to be given the initial temperature of the calorimeter.
 
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Pouyan said:
So we reduce 26 with the temprature of water for calorimeter ...is this always like this? If water is in the system should we find always the heat capacity of calorimeter with respect to water temprature ? What if water is not involved ?!I ask for an apology that I asked like this but I am a beginner...
thanks !
I think now you will have a clear idea after going through TSny's reply.
 

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