Specific heat capacity of calorimeter

Click For Summary

Homework Help Overview

The discussion revolves around calculating the heat capacity of a calorimeter in a thermal equilibrium scenario involving a piece of copper and water. The problem involves specific heat capacities and the application of the first law of thermodynamics.

Discussion Character

  • Conceptual clarification, Assumption checking, Problem interpretation

Approaches and Questions Raised

  • Participants explore the relationship between heat emitted by copper and heat absorbed by water and the calorimeter. Questions arise regarding the reference temperature for calculating the calorimeter's heat capacity and the assumptions made about thermal equilibrium.

Discussion Status

Participants are actively discussing the assumptions of thermal equilibrium and the implications for calculating heat capacity. Some guidance has been offered regarding the relationship between the temperatures of the water and calorimeter, but no consensus has been reached on the necessity of using water's temperature for the calorimeter's heat capacity calculation.

Contextual Notes

There is a mention of the initial temperatures of the calorimeter and water being the same, which is a key assumption in the problem. The discussion also highlights the potential complications if water is not involved in the system.

Pouyan
Messages
103
Reaction score
8
I've got a problem:
A piece of copper with mass m1 = 800 g and temperature t1 = 80 ° C is placed in a container with good thermal insulation. The vessel initially contains water with mass m2 = 500 g temperature t2 = 20 C. What is the calorimeter (including thermo meter) heat capacity if the end temperature is tf = 26 C?!

The solution is:

the specific heat capasity for copper: 0:39 kJ / kg.C
and for water: 18.4 kJ / kg.C
dQ copper = m1 * CCU * (t1-t0) = 16.85 kJ

dQ water = m2* CH20 * (t0-t1) = 12:54 kJ

According to the first law of thermodynamics, the amount of heat transferred to the calorimeter and thermometer:

dQ = dQ copper - dQ water = 4.31 kJ

But how can I find the heat capacity of the calorimeter?
I see a solution that I should do this: 4.31 kJ / (26-20) C

but why water in this case?! should I always find the specific heat capacity of the calorimeter or the thermometer with respect to the minimum tempraturen?!
 
Physics news on Phys.org
Heat capacity(not specific heat) is nothing but mass times specific heat. If h be the heat capacity of the calorimeter including thermometer and your calculation is correct, then
##h(26-20) = 4.31##
 
Korak Biswas said:
Heat capacity(not specific heat) is nothing but mass times specific heat. If h be the heat capacity of the calorimeter including thermometer and your calculation is correct, then
##h(26-20) = 4.31##

Should I think:

Q los = Q gain

and Q gain = Q water + Q calorimeter ?!
 
Pouyan said:
Should I think:

Q los = Q gain

and Q gain = Q water + Q calorimeter ?!

Heat emitted by piece of copper = heat absorbed by water + heat absorbed by calorimeter including thermometer.
It follows from the conservation of energy.
 
  • Like
Likes   Reactions: Pouyan
Korak Biswas said:
Heat emitted by piece of copper = heat absorbed by water + heat absorbed by calorimeter including thermometer.
It follows from the conservation of energy.
So we reduce 26 with the temprature of water for calorimeter ...is this always like this? If water is in the system should we find always the heat capacity of calorimeter with respect to water temprature ? What if water is not involved ?!I ask for an apology that I asked like this but I am a beginner...
thanks !
 
In a problem like this, it is assumed that the water and the calorimeter are initially in thermal equilibrium with each other before the copper is added. So, you can assume the calorimeter and the water have the same initial temperature (20 oC in this case.)

If there is no water so that the copper is placed in an empty calorimeter, then you would need to be given the initial temperature of the calorimeter.
 
  • Like
Likes   Reactions: Korak Biswas
Pouyan said:
So we reduce 26 with the temprature of water for calorimeter ...is this always like this? If water is in the system should we find always the heat capacity of calorimeter with respect to water temprature ? What if water is not involved ?!I ask for an apology that I asked like this but I am a beginner...
thanks !
I think now you will have a clear idea after going through TSny's reply.
 

Similar threads

  • · Replies 2 ·
Replies
2
Views
963
  • · Replies 6 ·
Replies
6
Views
2K
  • · Replies 7 ·
Replies
7
Views
2K
Replies
2
Views
3K
  • · Replies 3 ·
Replies
3
Views
2K
  • · Replies 16 ·
Replies
16
Views
5K
Replies
8
Views
2K
  • · Replies 9 ·
Replies
9
Views
16K
Replies
2
Views
2K
  • · Replies 12 ·
Replies
12
Views
3K