π
nasu said:
What do you mean by "axial arm speed"?
Under conditions of equilibrium, the distribution of velocity probabilities along any axis of a standard orthogonal tri-axial reference system is the same. That is, the mean velocity along the + arm of the x-axis is identical to the mean velocity along the – arm and is indeed identical to the mean velocity along any arm of any axis—no matter how the reference system is oriented. More interesting, it is identical to the mean velocity along all arms averaged together. That speed (v
p) is the mean axial arm speed of a general population of gas molecules. I use the “p” subscript to denote that the directional component of the velocity is “poly” directional.
This gives rise to the classical concept that the pressure of a gas (in the absence of unbalanced forces) is everywhere the same within that volume of gas. No matter where you postulate a surface, the impact rate of molecules impacting upon that surface (½nv
p) will be identical and the mean impulse per impact (2m
iv
i) will also be identical. Hence, the pressure (mean impact rate times mean impulse transferred per impact) will everywhere be the same.
However, when I used that term in my post, I was clearly referring to the mean axial arm impulse speed (v
i). This is the mean axial arm speed of the interactive molecular population, not the mean axial arm speed of the general population (v
p). The two have different parameters. The mean axial arm impulse speed is the axial arm speed of that select sub-population of molecules that are passing through an imaginary plane or impacting upon a surface. The speed is measured at the instant of passage or impact. The mean molecular axial arm impulse (v
i) speed is always higher than the mean molecular axial arm speed (v
p). The relationship between the two is always v
i = π/2 v
p (that's a pi symbol, not an n). The directional component of the mean axial arm impulse velocity is always normal to and toward the object of interest, be it an imaginary plane, a sensing surface, a raindrop, or anything else you can think of.