Spherical Symmetry & Electron Spin: An Exploration

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Discussion Overview

The discussion explores the relationship between electron spin angular momentum and spherically symmetrical potential energy functions, focusing on whether electrons can possess non-zero spin angular momentum in such contexts. The scope includes theoretical considerations and implications for atomic behavior.

Discussion Character

  • Exploratory, Technical explanation, Debate/contested

Main Points Raised

  • One participant questions if an electron in a spherically symmetrical potential can have non-zero spin angular momentum.
  • Another participant asserts that electrons, being spin-1/2 particles, always have non-zero spin angular momentum, which allows for two electrons in each orbital without violating the exclusion principle.
  • A different participant notes that electrons can also possess non-zero orbital angular momentum, providing an example with quantum numbers n=2, l=1.
  • One participant argues that any atom with net unpaired electrons will exhibit non-zero spin angular momentum, linking this to phenomena such as ferromagnetism.

Areas of Agreement / Disagreement

Participants express differing views on the implications of spherically symmetrical potentials for electron spin and orbital angular momentum, indicating that multiple competing perspectives remain unresolved.

Contextual Notes

Some statements depend on the definitions of angular momentum and the context of the discussion, particularly regarding the distinction between spin and orbital angular momentum.

Happiness
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Can an electron in a spherically symmetrical potential energy function have non-zero spin angular momentum?
 
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Always - it’s a spin-1/2 particle. This is why we find two electrons in each orbital without violating the exclusion principle.

[Edit: Having just read through the most recent updates to your other thread, this might be a good time to mention that people often say “angular momentum” instead of “orbital angular momentum” when the context makes it clear that we are not considering the spin so the orbital angular momentum is the total angular momentum]
 
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It can also have non-zero orbital angular momentum. n=2, l=1.
 
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Happiness said:
Can an electron in a spherically symmetrical potential energy function have non-zero spin angular momentum?

Any atom (all of which are solved via a spherically symmetry electric potential) that has net unpaired electrons will exhibit a non-zero spin angular momentum... not to mention, orbital angular momentum. That is why we have ferromagnetism, etc.

Zz.
 
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