Stationary states vs. the unitary time evolution operator

In summary, stationary states in quantum mechanics are states of a system that do not change with time and are characterized by a definite energy. The unitary time evolution operator is a mathematical operator that describes the evolution of a quantum system over time and ensures the total probability remains constant. These two concepts are closely related and are fundamental in understanding the behavior of a quantum system. While stationary states provide a basis for describing the system, a combination of these states and the unitary time evolution operator is necessary to fully describe its behavior.
  • #1
LarryS
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In QM, states evolve in time by action of the Time Evolution Unitary Operator, U(t,t0). Without the action of this operator, states do not move forward in time. Yet even stationary states, like an eigenstate of energy, still contain a time variable – they oscillate in time at a fixed frequency.

To me, the above implies that there are TWO types of “time”, one for the fixed oscillations of stationary states and the other as arguments for that unitary operator.

Comments?

As always, thanks in advance.
 
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  • #2
referframe said:
In QM, states evolve in time by action of the Time Evolution Unitary Operator, U(t,t0). Without the action of this operator, states do not move forward in time.

"Without the action of this operator" is meaningless; there's no way to somehow stop the operator from working so we can see what happens without it. The operator is a description of how states evolve in time; it's not a thing that could either be applied to the states or not. (This, btw, is a fundamental difference between the time evolution operator and operators describing things that are done to quantum systems in experiments; we can choose to apply or not apply the latter, but we can't choose to apply or not apply the former.)

referframe said:
even stationary states, like an eigenstate of energy, still contain a time variable – they oscillate in time at a fixed frequency.

More precisely, their phases change with time at a fixed frequency. But multiplying a quantum state by a phase doesn't change any observables, so all of the observables of a stationary state do not change with time.

referframe said:
To me, the above implies that there are TWO types of “time”, one for the fixed oscillations of stationary states and the other as arguments for that unitary operator.

No, they're the same thing. The argument of the unitary operator is the same variable that governs the phases of stationary states. Why? Because the change of phase of a stationary state is the action of the unitary time evolution operator. It's not some separate phenomenon.
 
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  • #3
PeterDonis said:
No, they're the same thing. The argument of the unitary operator is the same variable that governs the phases of stationary states. Why? Because the change of phase of a stationary state is the action of the unitary time evolution operator. It's not some separate phenomenon.

If the changes of phase of a stationary state is the action of the unitary time evolution operator, then why have a unitary time evolution operator at all? The presence of the "t" variable in eiωt would be sufficient.
 
  • #4
referframe said:
The presence of the "t" variable in eiωt would be sufficient.

##e^{i \omega t}## is the unitary time evolution operator. You've just limited it to the case of a single stationary state, i.e., an eigenstate of the Hamiltonian with eigenvalue ##\omega## (in "natural" units where ##\hbar = 1##). The general unitary time evolution operator is ##e^{i \hat{H} t}##, which can be applied to any state; applying it to an eigenstate of ##\hat{H}## gives what you wrote.
 

1. What are stationary states in quantum mechanics?

Stationary states in quantum mechanics refer to the states of a system that do not change over time. They are represented by eigenstates of the Hamiltonian operator and have a definite energy value. In other words, the probability of finding a particle in a stationary state remains constant over time.

2. How do stationary states differ from non-stationary states?

Non-stationary states, also known as transient states, are states that change over time. They are not represented by eigenstates of the Hamiltonian operator and do not have a definite energy value. The probability of finding a particle in a non-stationary state changes over time.

3. What is the unitary time evolution operator?

The unitary time evolution operator is a mathematical operator that describes the time evolution of a quantum system. It is represented by the exponential of the Hamiltonian operator multiplied by the imaginary unit. This operator is used to calculate the state of a system at any given time.

4. How does the unitary time evolution operator relate to stationary states?

The unitary time evolution operator acts on a quantum state to evolve it over time. In the case of stationary states, the operator has no effect since these states do not change over time. This means that the state remains in a stationary state for all times.

5. What is the significance of stationary states and the unitary time evolution operator in quantum mechanics?

Stationary states and the unitary time evolution operator are fundamental concepts in quantum mechanics. They allow us to understand the behavior of quantum systems and make predictions about their evolution over time. The concept of stationary states is also crucial in the study of energy levels and transitions between them in quantum systems.

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