Statistical mechanics and macrostates

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SUMMARY

The discussion centers on the concept of macrostates in statistical mechanics, specifically regarding a system of atoms in a box divided by a partition. It is established that for n identical atoms, there are n + 1 macrostates, as the number of atoms on one side can range from 0 to n. The conversation also highlights the importance of particle statistics, mentioning Maxwell-Boltzmann, Fermi-Dirac, and Bose-Einstein statistics, which apply depending on whether the particles are identical or distinguishable. The macrostate can be represented as an n-tuple for distinguishable particles or as a uniform distribution for indistinguishable particles.

PREREQUISITES
  • Understanding of statistical mechanics principles
  • Familiarity with macrostates and microstates
  • Knowledge of particle statistics: Maxwell-Boltzmann, Fermi-Dirac, and Bose-Einstein
  • Basic concepts of distinguishable vs. indistinguishable particles
NEXT STEPS
  • Explore the implications of Maxwell-Boltzmann statistics in classical systems
  • Investigate Fermi-Dirac statistics and its application to fermions
  • Learn about Bose-Einstein statistics and its relevance to bosons
  • Study the mathematical representation of macrostates and microstates in statistical mechanics
USEFUL FOR

This discussion is beneficial for students and professionals in physics, particularly those studying statistical mechanics, thermodynamics, and quantum statistics. It is also relevant for researchers exploring the behavior of different types of particles in statistical systems.

Nylex
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In my Statistical Physics and Entropy module, we did something about atoms in a box with an imaginary partition down the middle, so atoms could either be on the left or the right. If there were 4 atoms in the box, the system would have 5 macrostates. If there were 8, there would be 9.

Is is true that for n atoms in such a box, there are n + 1 macrostates, for any n?

Thanks.
 
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Wrt what statistics...?If those atoms are identical,then u'd have 3 possible cases:Maxwell-Boltzmann statistics,Fermi-Dirac and Bose-Einstein.

If they're not identical,then it wouldn't matter what classical/quantum description u adopt...

Either way,a macrostate would be described through a n-tuplet (1,2,...,n) for distinguishable particles or (1,1,...,1) for indistinguishable particles.

Daniel.
 
If your macrostate is defined as the number of atoms in the left side of the box, then yes, since you can have 0,1,2,..., or n atoms on the left.
 
dextercioby said:
Wrt what statistics...?If those atoms are identical,then u'd have 3 possible cases:Maxwell-Boltzmann statistics,Fermi-Dirac and Bose-Einstein.

If they're not identical,then it wouldn't matter what classical/quantum description u adopt...

Either way,a macrostate would be described through a n-tuplet (1,2,...,n) for distinguishable particles or (1,1,...,1) for indistinguishable particles.

Daniel.

As usual, I have no idea what you mean.

Galileo said:
If your macrostate is defined as the number of atoms in the left side of the box, then yes, since you can have 0,1,2,..., or n atoms on the left.

Thanks.
 
If those 4 particles are photons,how many macrostates do you have there...?

Daniel.
 
dextercioby said:
If those 4 particles are photons,how many macrostates do you have there...?

Daniel.

:confused:
 
It was the easiest example to what i'd been trying to tell...It matters what kind of particles you have there...It's not the same thing if they're billiard balls,fermions or bosons...:wink:

Daniel.
 

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