Summing reactions/rate constants

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SUMMARY

The discussion focuses on determining the rate constant for the combined reaction A + 2B -> D + E + F, derived from two known reactions: A + B -> C + D and C + B -> E + F. To accurately calculate the rate constant for the sum of these reactions, additional information regarding the lability and stability of the reactants and products is essential. The participants emphasize the importance of considering the system's conditions, specifically that the reactions are not reversible and all species involved are stable.

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Chemists, chemical engineers, and students studying reaction kinetics who are interested in understanding how to derive rate constants for combined reactions.

Sosi
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Hi!

I have a couple of reactions whose rate constants are known:

A + B -> C + D (reaction 1)
C + B -> E + F (reaction 2)

and I want to know the rate constants of the sum of these reactions. That is:

A + 2B -> D + E + F (reaction 3)

How may I know the rate constant for reaction 3, assuming that I know the rate constants for reaction 1 and 2?

Thanks for all the help!
 
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Sosi said:
Hi!

I have a couple of reactions whose rate constants are known:

A + B -> C + D (reaction 1)
C + B -> E + F (reaction 2)

and I want to know the rate constants of the sum of these reactions. That is:

A + 2B -> D + E + F (reaction 3)

How may I know the rate constant for reaction 3, assuming that I know the rate constants for reaction 1 and 2?

Thanks for all the help!

You need to provide some additional information about the lability of the reactions (1 and 2) before you can proceed.
 
gabriels-horn said:
You need to provide some additional information about the lability of the reactions (1 and 2) before you can proceed.

all the species from reactions 1 and 2 are stable. I was advised to consider an open system in which the reactions were not reversible. Does this help? I'm not seeing how I can use this information...

Thanks!
 

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