Superconductivity: Current and Magnetic Field Limitations

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Discussion Overview

The discussion revolves around the limitations of superconductivity in materials, specifically focusing on the critical current density (Jc) and critical magnetic field (Hc) that, when exceeded, lead to the destruction of superconductivity. Participants explore atomic and chemical factors influencing these limits, as well as theoretical frameworks such as BCS theory.

Discussion Character

  • Technical explanation
  • Conceptual clarification
  • Debate/contested

Main Points Raised

  • One participant questions the atomic causes for the destruction of superconductivity when the current limit is breached, seeking a deeper understanding of the phenomenon.
  • Another participant suggests that the magnetic field generated by the current must be canceled, indicating that this cancellation is effective only up to a certain point.
  • A later reply reiterates the previous point but seeks further clarification on the underlying reasons for this limitation.
  • Several participants reference BCS theory, explaining that superconductivity arises from the formation of Cooper pairs and that exceeding Jc or Hc disrupts this pairing due to increased kinetic energy of electrons.
  • There is mention of the critical temperature (Tc) and its relation to the binding energy of Cooper pairs, with specific values provided for conventional and high-temperature superconductors.
  • One participant concludes that increasing Jc and Hc is contingent upon increasing Tc, although this is presented as a response rather than a universally accepted conclusion.

Areas of Agreement / Disagreement

Participants express various viewpoints regarding the mechanisms behind the limitations of superconductivity, with some agreement on the role of Cooper pairs and BCS theory, but no consensus on the atomic details or implications of these mechanisms.

Contextual Notes

Participants reference specific theoretical frameworks and values related to superconductivity, but the discussion does not resolve the complexities or dependencies involved in these phenomena.

VictorMedvil
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Why when a certain current limit is breached is superconductivity destroyed in a material, what atomically causes this effect when J > Jc? Secondary question what causes H0's value to be higher or lower atomically and chemically for a given material?

Limits-of-Superconductivity.jpg
 
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It's the same effect, basically. The current inside the superconductor produces a magnetic field that needs to be canceled (which effectively means the current flows on the surface, approximately), that only works up to some point.
 
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mfb said:
It's the same effect, basically. The current inside the superconductor produces a magnetic field that needs to be canceled (which effectively means the current flows on the surface, approximately), that only works up to some point.
But why? I understand that part of it.
 
According to the BCS theory, superconducting phenomena occur when two electrons couple to form a Cooper pair (http://hyperphysics.phy-astr.gsu.edu/hbase/Solids/coop.html).

Kevin A. Delin and Terry P. Orlando in Chapter 122 „Superconductivity“ in „The Engineering Handbook“ (ed. Richard C. Dorf):

“If we prevent the Cooper pairs from forming by ensuring that all the electrons are at an energy greater than the binding energy, we can destroy the superconducting phenomenon. This can be accomplished, for example, with thermal energy. In fact, according to the BCS theory, the critical temperature, ##T_c##, associated with this energy is

$$\frac {2\Delta} {k_BT_c} \approx 3.5$$

where ##k_B## is Boltzmann’s constant. For low critical temperature (conventional) superconductors, ##2Δ## is typically on the order of ##1 meV##, and we see that these materials must be kept below temperatures of about ##10 K## to exhibit their unique behavior. Superconductors with high critical temperature, in contrast, will superconduct up to temperatures of about ##100 K##, which is attractive from a practical view because the materials can be cooled cheaply using liquid nitrogen. A second way of increasing the energy of the electrons is electrically driving them. In other words, if the critical current density, ##J_c##, of a superconductor is exceeded, the electrons have sufficient kinetic energy to prevent the formation of Cooper pairs. The necessary kinetic energy can also be generated through the induced currents created by an external magnetic field. As a result, if a superconductor is placed in a magnetic field larger than its critical field, ##H_c##, it will return to its normal metallic state. To summarize, superconductors must be maintained under the appropriate temperature, electrical current density, and magnetic field conditions to exhibit its special properties.”
 
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Lord Jestocost said:
According to the BCS theory, superconducting phenomena occur when two electrons couple to form a Cooper pair (http://hyperphysics.phy-astr.gsu.edu/hbase/Solids/coop.html).

Kevin A. Delin and Terry P. Orlando in Chapter 122 „Superconductivity“ in „The Engineering Handbook“ (ed. Richard C. Dorf):

“If we prevent the Cooper pairs from forming by ensuring that all the electrons are at an energy greater than the binding energy, we can destroy the superconducting phenomenon. This can be accomplished, for example, with thermal energy. In fact, according to the BCS theory, the critical temperature, ##T_c##, associated with this energy is

$$\frac {2\Delta} {k_BT_c} \approx 3.5$$

where ##k_B## is Boltzmann’s constant. For low critical temperature (conventional) superconductors, ##2Δ## is typically on the order of ##1 meV##, and we see that these materials must be kept below temperatures of about ##10 K## to exhibit their unique behavior. Superconductors with high critical temperature, in contrast, will superconduct up to temperatures of about ##100 K##, which is attractive from a practical view because the materials can be cooled cheaply using liquid nitrogen. A second way of increasing the energy of the electrons is electrically driving them. In other words, if the critical current density, ##J_c##, of a superconductor is exceeded, the electrons have sufficient kinetic energy to prevent the formation of Cooper pairs. The necessary kinetic energy can also be generated through the induced currents created by an external magnetic field. As a result, if a superconductor is placed in a magnetic field larger than its critical field, ##H_c##, it will return to its normal metallic state. To summarize, superconductors must be maintained under the appropriate temperature, electrical current density, and magnetic field conditions to exhibit its special properties.”

So the only way to increase Jc and Hc is to increase Tc, thanks for answering this question Lord Jestocost.
 

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