Terms of second order and fourth order what does this MEAN?

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SUMMARY

The discussion centers on the interpretation of "second order" and "fourth order" terms in the context of the Born-Oppenheimer approximation, as detailed in the paper by Born and Oppenheimer. Specifically, it clarifies that nuclear vibrations correspond to second order terms (proportional to a²) and rotations to fourth order terms (proportional to a⁴), while first and third order terms vanish. Additionally, the conversation touches on the meaning of error estimates expressed as \mathcal{O}(\alpha), confirming that it indicates the error's magnitude is bounded by a constant multiplied by |\alpha| as \alpha approaches zero.

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AxiomOfChoice
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Terms of "second order" and "fourth order"...what does this MEAN?!

I am reading the paper written by Born and Oppenheimer that explains the development of the Born-Oppenheimer approximation. The paper contains the following cryptic (to me) statement:

"The nuclear vibrations correspond to terms of second order and the rotations to fourth order in the energy, while the first and third order terms vanish."

What, EXACTLY, is a "term of second order...in the energy?" (Or fourth order, for that matter?) I'm sure this is something I should know from freshman calculus, but this vernacular gets used a lot, and my understanding of it is muddled - it just is. Should I feel bad about this?
 
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AxiomOfChoice said:
"The nuclear vibrations correspond to terms of second order and the rotations to fourth order in the energy, while the first and third order terms vanish."

What, EXACTLY, is a "term of second order...in the energy?" (Or fourth order, for that matter?)

Hi AxiomOfChoice! :wink:

It just means that if you expand it as ∑ anEn ,

then the nuclear vibrations are proportional to a2,

the rotations are proportional to a4,

and a1 = a3 = 0. :smile:
 


Physicists take taylor series _all the time_ and don't think twice about it.
 


Thanks guys. On this same subject, when someone notes that "error estimates are \mathcal{O}(\alpha)" for some parameter \alpha, does this translate into English as "error estimates are order \alpha?" And, if it does, what does that mean? Does it mean there is a constant c such that the magnitude of the error is less than c|\alpha| as \alpha \to 0? And is it understood that c = 1, such that all it amounts to is that, if \Delta x is the error, we have |\Delta x| \leq |\alpha|?
 
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