The battery and its potential difference

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Discussion Overview

The discussion revolves around understanding the potential difference in batteries, including how it is defined and the underlying mechanisms that produce electromotive force (emf). Participants explore both chemical and physical explanations, with varying levels of comfort regarding chemistry.

Discussion Character

  • Exploratory
  • Technical explanation
  • Conceptual clarification
  • Debate/contested

Main Points Raised

  • Some participants inquire about the nature of potential difference in batteries and whether both electric potentials can be positive.
  • One participant explains that batteries consist of two terminals made from different metals, where the more reactive metal serves as the negative terminal and the less reactive as the positive terminal, with electron flow completing the circuit.
  • Another participant expresses uncertainty about the possibility of both potentials being positive without charging the entire battery, suggesting that potential is referenced to ground.
  • Several participants request a physical explanation of battery operation, expressing discomfort with chemical details.
  • One participant emphasizes that understanding battery function inherently requires some knowledge of chemistry, while others seek to avoid chemical explanations.
  • A later reply illustrates how potential differences can exist in a series of cells, providing an example with specific voltage values to clarify the concept.

Areas of Agreement / Disagreement

Participants exhibit a mix of agreement and disagreement regarding the necessity of chemistry to explain battery function. While some assert that chemistry is essential, others prefer a purely physical explanation. The discussion remains unresolved on the best approach to understanding battery operation.

Contextual Notes

Participants express varying levels of understanding and comfort with chemistry, which influences their ability to engage with the topic. There are also references to specific voltage scenarios that may not be universally applicable, highlighting the complexity of potential differences in practical applications.

Who May Find This Useful

This discussion may be useful for individuals interested in the principles of battery operation, particularly those seeking to understand the relationship between potential difference and chemical processes, as well as those looking for physical interpretations of electrical concepts.

amjad-sh
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Hello everybody :smile:
can anybody explain to me why there is potential difference in the battery (and when we say the potential difference of the battery is Va-Vb =12 v can both electric potentials be positive for example Va=20v and Vb =8v ) . From the last , can somebody illustrate to me in a deep way how the battery works and how it produce emf..?
and thanks a lot :smile:.
 
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Batteries have a positive terminal and a negative terminal.Normally,a simple battery is a cell.(As far as I know)The cells works by electrolysis.Two metals with a different reactivity is used.The two metal is then dipped into the electrolyte and connected with a wire above the electrolyte.The electrons flow from the more reactive metal to the less reactive metal,as more reactive metals tends to lose electrons more easily(not through the electrolyte,but through the wire above it,which connects two metals to complete the circuit.).So the more reactive metal is the negative terminal and the less reactive metal,the positive terminal.The greater the difference in the reactivity,the greater the emf produced.
(If you know chemistry,I will explain it more)
 
amjad-sh said:
Hello everybody :smile:
can anybody explain to me why there is potential difference in the battery (and when we say the potential difference of the battery is Va-Vb =12 v can both electric potentials be positive for example Va=20v and Vb =8v ) .

I don't think the electric potentials can both be positive or negative unless you electrically charge the whole battery. (which I've never heard of) Still, this potential would be with reference to ground, not between the terminals, so it doesn't really matter.
 
the problem is that I am weak in chemistry . if you can illustrate in a physical way?
 
amjad-sh said:
the problem is that I am weak in chemistry . if you can illustrate in a physical way?
Electrolysis is the process of decomposition of a molten or ionic aqueous salt solution using electricity.When the two metal is connected by a wire,the more reactive metal tends to lose electrons,so electron travels through the wire to the less reactive metal.(it is now dipped into the electrolyte(molten or aqueous salt solution,acid or alkali))the electron transfer makes the more reactive metal positively charged,making it the anode(which attracts negative ions or anions)Anions in the electrolyte gets discharged there,giving electrons to the metal.On the other hand,the less reactive metal is now negatively charged(as electron has traveled to it).It becomes cathode(attracts cations or positive ions)Cations gets discharged there taking electrons away from the less reactive metal.So,the electrons now travel round the circuit,until the electrolyte depletes.
 
thanks for your effort. But I just want to understand it physically. I know that V1=Qk/r1 V2=Qk/r2 V1-V2 produce emf , I want it to be illustrated in a physical way without any chemical details as much as possible .
 
amjad-sh said:
thanks for your effort. But I just want to understand it physically. I know that V1=Qk/r1 V2=Qk/r2 V1-V2 produce emf , I want it to be illustrated in a physical way without any chemical details as much as possible .

I'm not sure it's possible to understand how a battery works without getting into some basic chemistry.
 
I am with Drakkith on this, a battery is a chemical device. To understand how one works requires chemistry. No satisfactory explanation can be given without mention of chemistry.
 
ok thanks ..
 
  • #10
and when we say the potential difference of the battery is Va-Vb =12 v can both electric potentials be positive for example Va=20v and Vb =8v

Yes.

I could take a 12V battery and put it in series with a 1000 V DC source and the battery terminals could be..

-ve terminal 1000V
+ve terminal 1012V

If you have a toy that uses three 1.5V cells in the battery the voltages would typically be

Cell 1 -ve = 0V (I define it so)
Cell 1 +ve = 1.5V
Cell 2 -ve = 1.5V
Cell 2 +ve = 3V
Cell 3 -ve = 3V
Cell 3 +ve = 4.5V

Overall voltage of the battery is Cell 3 +ve minus Cell 1 -ve which is 4.5 - 0 = 4.5V

I run the toy across a nylon carpet so it picks up some static electricity, then relative to Earth the voltages might become

Cell 1 -ve =10,000V
Cell 3 +ve = 10,004.5V
 
  • #11
amjad-sh said:
thanks for your effort. But I just want to understand it physically. I know that V1=Qk/r1 V2=Qk/r2 V1-V2 produce emf , I want it to be illustrated in a physical way without any chemical details as much as possible .

http://forum.allaboutcircuits.com/blog.php?b=588
 

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