What is the distinction between thermal and internal energy?

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Discussion Overview

The discussion revolves around the distinction between thermal energy and internal energy, exploring definitions, interpretations, and their implications in thermodynamics. Participants examine the relationship between kinetic and potential energy in these contexts.

Discussion Character

  • Conceptual clarification
  • Debate/contested

Main Points Raised

  • Some participants suggest that thermal energy and internal energy are essentially the same, both referring to the sum of kinetic and potential energy associated with atomic and molecular interactions.
  • Others argue that internal energy is a more general term than thermal energy, with thermal energy specifically relating to the internal energy due to temperature.
  • One participant emphasizes that thermal energy can be viewed as a form of internal energy, highlighting the definitions involved.
  • A later reply notes that internal energy is a state function, while heat and work depend on the path of transfer, which introduces a distinction in their treatment in thermodynamics.
  • Another participant provides an example involving a glass of water to illustrate the concept of internal energy at the microscopic level, noting that macroscopic motion does not necessarily change the internal energy.

Areas of Agreement / Disagreement

Participants express differing views on the definitions and relationships between thermal energy and internal energy, indicating that the discussion remains unresolved with multiple competing interpretations.

Contextual Notes

There are limitations in the definitions provided, and the discussion reflects varying interpretations of thermal and internal energy, as well as their roles in thermodynamics.

TT0
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What is the difference? I read that thermal energy includes both kinetic and potential energy but isn't that what internal energy is?

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I think there are actually no differences between the two terms. Both internal energy and thermal energy of a system refers to the sum of KE and PE, and both are primarily determined by the collisions and interactions between the atoms and molecules in the system.
However, internal energy should be a more general term than thermal energy. In terms of thermodynamics, the term thermal energy would be used to replace tge term internal energy.
 
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It is just a matter of definition. Thermal energy is primarily defined as the internal energy of a system. Then, thermal energy can be referred as a form of internal energy.
 
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TT0 said:
What is the difference? I read that thermal energy includes both kinetic and potential energy but isn't that what internal energy is?
In thermodynamics , thermal energy refers to the internal energy present in a system due to only to its temperature.

It is often most convenient and precise to think of heat as the transfer of energy,
Heat and work depend on the path of transfer and are not state functions, whereas internal energy is a state function.

Internal energy is defined as the energy associated with the random motion of molecules.

It is separated in scale from the macroscopic ordered energy associated with moving objects; it refers to the invisible on the atomic and microscopic molecular scale.

An example- a glass of water sitting on a table at room temperature has no apparent energy.
. But on the microscopic scale it can be seen as mass of high speed molecules traveling at hundreds of meters per second.
If the water were tossed across the room, this microscopic energy would not necessarily be changed when we superimpose a large scale motion on the water as a whole. so it is state function .

see wiki/hyperphysics site for a discussion.<http://hyperphysics.phy-astr.gsu.edu/hbase/thermo/inteng.html>
 
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I see thanks
 

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