[Thermo] Derivation of compressibility factor vs reduced pressure

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SUMMARY

The discussion focuses on deriving the compressibility factor (Z) as a function of reduced pressure (Pr) using the Van der Waals equation of state. The compressibility factor is defined as Z = (Pv)/(RT) and is influenced by the reduced pressure, which is calculated as P divided by the critical pressure. The user is guided to utilize propane's critical properties (Tc = 370 K, Pc = 42.7 bar) to generate a graph by varying pressure and calculating specific volume from propane tables. The mathematical derivation involves solving the cubic equation PV³ - (Pb + RT)V² + aV - ab = 0.

PREREQUISITES
  • Understanding of the Van der Waals equation of state
  • Knowledge of compressibility factor and its significance
  • Familiarity with critical properties of gases, specifically propane
  • Ability to solve cubic equations and interpret graphical data
NEXT STEPS
  • Learn how to derive compressibility charts from experimental data
  • Study the properties of various gases, focusing on critical temperature and pressure
  • Explore the application of the Van der Waals equation in real gas behavior
  • Investigate numerical methods for solving cubic equations in thermodynamics
USEFUL FOR

Students and professionals in chemical engineering, thermodynamics, and physical chemistry who are involved in gas behavior analysis and compressibility factor calculations.

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Homework Statement


derivation of compressibility factor vs. reduced pressure
I am supposed to derive the graph by solving equations
Diagramma_generalizzato_fattore_di_compressibilit%C3%A0.jpg



Homework Equations


Van der Waals equation of state
compressibility factor, Z = (Pv)/(RT)
reduced pressure = P/critical pressure
Z = f(Tr, Pr)


The Attempt at a Solution


I sat for 12 hours attempting to find a solution but just spent time trying to understand what I was doing instead.
Is there a way to get the graph mathematically without using any values for critical pressure or temperature?

Thank you!
 
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Compressibility charts are derived from experimental data from 10 gases such as propane, Nitrogen, Carbon Dioxide etc. Select a gas you have properties for such as propane. Tc propane is 370 K. Pc propane is 42.7 bar. Assume a constant temperature of let's say 555 K to generate the Tr=1.5 line. Vary pressure from 42.7 to 300 bars (Pr 1 to 6). Use propane tables to find v (specific volume) solve for Z. Plot Tr(Z,Pr)
 
After solving the Van der Waals equation for the compressibility factor and
deriving the critical temperature, pressure, and volume

knowing that a horizontal inflection point occurs on the isotherm at critical point

am I supposed to solve PV3-(Pb+RT)V2+aV-ab=0
for the cubic root?
 

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