Thermodynamics - monotomic/diatomig gas heat capacity question

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Monatomic gases like helium require less heat than diatomic gases like hydrogen for the same temperature increase due to differences in their molecular structure and energy modes. Helium, being monatomic, has fewer degrees of freedom, while diatomic gases can store energy in rotational and vibrational modes in addition to translational motion. The discussion references the equipartition theorem, which explains how energy is distributed among these modes. Understanding the heat capacities (Cp and Cv) of these gases is essential for grasping their thermal behavior. This fundamental difference in molecular behavior underlies the varying heat capacities of monatomic and diatomic gases.
p.ella
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Thermodynamics -- monotomic/diatomig gas heat capacity question

Homework Statement



GRADE 12 CHEMISTRY: Why would a monotomic gas like Helium require less heat than a diatomic gas like hydrogen to undergo the same temperature increase?


Homework Equations



q=mcΔT


The Attempt at a Solution



I think it has something to do with bonds and rotational/translational/vibrational energy of molecules but don't know exactly help

Thank you everyone!
 
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Hello p.ella,

The answer to your question maybe twofold.

First ask yourself this: How do the CP and CV values of helium compare with other gases?

Secondly, What kind of inter-molecular forces act between helium molecules? How do they compare with other gases?
 
Sunil Simha said:
Secondly, What kind of inter-molecular forces act between helium molecules? How do they compare with other gases?
Sorry Sunil, but I don't think that intermolecular forces are the right way to go.

p.ella, have you heard of the equipartition theorem?
 
DrClaude said:
Sorry Sunil, but I don't think that intermolecular forces are the right way to go.

p.ella, have you heard of the equipartition theorem?

Thanks anways Sunil :)

And no, I haven't, not yet atleast :)
 
p.ella said:
And no, I haven't, not yet atleast :)
That makes things a bit more difficult, but let's try it this way.

When heat is put into a monatomic gas, what changes?

If you have a diatomic molecule instead, what more can happen (in addition to what you just answered for the monatomic gas)?
 

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