Thomas-Fermi Model: Comparison with Atomic Experiments

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SUMMARY

The Thomas-Fermi model is primarily utilized for qualitative analysis of many-electron atoms, as it provides poor approximations for energy levels compared to experimental measurements. The model assumes that electrons move freely without the influence of nuclear potential, which oversimplifies the complexities of atomic interactions. A referenced paper, available at JETP, discusses the discrepancies between the model's predictions and actual atomic energy levels. Overall, while the Thomas-Fermi model offers insights, it is not reliable for precise calculations.

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blue_leaf77
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I'm reading the Thomas-Fermi model for many electrons atom. However the book I'm reading doesn't seem to provide a comparison between the result of calculation using this method with experimental measurement. I wonder if this method gives a good approximation at all. So, I would appreciate if somebody can provide me a link which discusses the comparison with experiments. e.g. the energy levels of some atoms.
 
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That's what I suspected though, the method begins with the assumption that the electrons move freely under no influence of any potential around the nucleus and that sounds to be oversimplification.
Thanks anyway for the paper.
 
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