Trying to understand the Brillouin zone

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SUMMARY

The discussion focuses on the Brillouin zone's relationship to electron states, specifically addressing the band structure of silicon as illustrated in the provided diagram. The user questions how an electron at the Gamma point (K=0) can possess energy and why Gamma appears twice in the band structure. It is clarified that the wavevector describes phase variation across elementary cells, and the energy of electrons in a crystal can be similar to that of free atoms, regardless of their wavevector.

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  • Understanding of Brillouin zones in solid-state physics
  • Familiarity with band structure diagrams
  • Knowledge of wavevectors and their significance in quantum mechanics
  • Basic concepts of electron states in crystalline materials
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  • Study the concept of Brillouin zones in detail using "Solid State Physics" by Ashcroft and Mermin
  • Explore band structure calculations using tools like GPAW or VASP
  • Learn about the significance of wavevectors in quantum mechanics and their role in electron behavior
  • Investigate the relationship between electron states and crystal symmetry
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phrygian
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I am having a really hard time understanding how the Brillouin zone relates to electron states and have a couple of questions that might help clear it up for me.

For a band structure like this:

https://wiki.fysik.dtu.dk/gpaw/_images/silicon_banddiagram.png

I know that the different symbols on the bottom correspond to different points in the Brillouin zone. Gamma is the center of the Brillouin zone with K=0, so how can an electron with that wavevector have any energy? And why does Gamma appear on the bottom twice?

Do these diagrams mean that when an electrons wavevector increases in magnitude it also must point in a different direction? And what do these states mean, that the electrons are plane waves traveling in one direction?

Thanks a lot for the help, it would really be great to finally understand these concepts.
 
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The wavevector only describes the variation of the phase going from elementary cell to elementary cell. But this does not exclude a variation of phase or more generally wavefunction (and accompanying kinetic energy) within an elementary cell. E.g. think about a crystal made up of helium atoms. The energy of the lowest band is approximately equal to that in a free helium atom irrespective of the phase (k vector) with which the wavefunctions of different atoms are superposed.
 

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