Understanding Energy of Particles with 'x' Degrees of Freedom

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SUMMARY

The discussion centers on the application of the Law of Equipartition of Energy, which states that each degree of freedom contributes (1/2)kT to the average thermal energy of a system. For a particle with 'x' degrees of freedom, the average energy is expressed as xkT/2. The participants explore the implications of the equation E = ax^6, emphasizing that this relationship holds under specific assumptions where terms are proportional to coordinate or momentum squared. The partition function Z is derived as Z = ∫e^(-αx^6)dx, where α = a/kT, leading to the calculation of energy using E = kT^2 d[ln Z]/dT.

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tanaygupta2000
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Homework Statement
Consider a system with a large number of non interacting particles at temperature T. Each particle has energy given by E = ax^6 associated with the degree of freedom x. Evaluate the mean energy per particle associated with this degree of freedom.
Relevant Equations
E = 3/2 kT
I've learned that for a particle having 3 degrees of freedom, its average energy is 3/2 kT.
So for a particle having 'x' degrees of freedom, its energy should be xkT/2.
So what is the use of given E = ax6 here?
Please help!
 
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Look up what exactly the equipartition theorem says. The devil is in the details.
 
vela said:
Look up what exactly the equipartition theorem says. The devil is in the details.
According to Law of Equipartition of Energy, each degree of freedom in a system of particles contributes (1/2)kT to the thermal average energy of the system.
So for x degrees of freedom of each particle in a system of particles, the thermal average energy of the system should be xkT/2.
And it is given that each particle has energy given by E = ax6.
 
That's based on certain assumptions. What are those assumptions?
 
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vela said:
That's based on certain assumptions. What are those assumptions?
Okay now I understood.
The above expression holds only when each term is proportional to either a coordinate or momentum squared.
In this case, we similarly have E = ax6 ∝ (x3)2

So we have to use for Partition function,
Z = ∫e-ax6/kTdx = ∫e(-a/kT)× (x6)dx

Let (a/kT) = α
=> Z = ∫e-αx6 dx

Since
Capture.PNG

So we can obtain Z and finally E using E = kT2 d[ln Z]/dT
Is this correct ?
 
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