Understanding the Dissolution of Zinc in a Galvanic Half-Cell

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Discussion Overview

The discussion centers around the dissolution of zinc in a galvanic half-cell, exploring the reactions involved when zinc is placed in zinc sulfate solution. Participants examine the mechanisms behind electron movement, the nature of redox reactions, and the conditions necessary for these processes to occur.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested
  • Conceptual clarification

Main Points Raised

  • One participant questions the specific reaction that causes zinc to dissolve and whether electrons are repelled by the solution or by other zinc atoms.
  • Another participant references external material on redox reactions, suggesting a need for further understanding.
  • A participant expresses confusion about whether the dissolution of zinc is due to a reaction with the solution or attraction to the positive electrode, raising a question about electron excess when electrodes are not connected.
  • There is a discussion about the necessity of electrical neutrality in electrodes and whether they can have a voltage.
  • One participant inquires if a redox reaction can occur simply by placing zinc and copper together without oxidizing or reducing agents.
  • A question is posed regarding whether a reaction between zinc and copper ions can occur without a solution, speculating on the energy dynamics involved.
  • Another participant seeks clarification on what specifically causes zinc atoms to dissolve into the solution and whether they react with other ions present.

Areas of Agreement / Disagreement

Participants express various viewpoints and uncertainties regarding the mechanisms of electron movement and the conditions required for redox reactions. No consensus is reached on these points, and multiple competing views remain throughout the discussion.

Contextual Notes

Participants highlight limitations in their understanding of the interactions between zinc atoms, ions in solution, and the role of electrodes in galvanic cells. There are unresolved questions about the nature of the reactions and the conditions under which they occur.

Who May Find This Useful

This discussion may be of interest to students and enthusiasts of electrochemistry, particularly those seeking to understand the principles of galvanic cells and redox reactions.

Slava
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In a standard galvanic half-cell when Zinc rode is placed into the Zinc sulphate. What is the reaction which makes zinc to dissolve and fell into the solution. Why do electrons move away from the sides of the electrode? Are they repelled by the solution or by other ZN atoms on the electrode which haven't been ionized yet?
 
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From the link which you posted it is said that: In this cell the zinc metal has a tendency to dissolve as ions leaving its electrons on the electrode.

I can't get the order: whether it is Reaction with the solution which causes electrons to fly away from Zn metal, or it is the attraction from the positive electrode which attracts loosely bound Zn electrons and as soon as Zinc start lacking electrons it will become Zn2+ and mix with the solution. If it is the latter case then when the electrodes are not connected will there be an excess of electrons on the negative terminal of the battery

This is what is unclear for me. I understand how the redox reaction works but I can't understand how the half-redox reaction works.

Thank you for your response.
 
The electrodes themselves must be electrically neutral and thus there will be no voltage? Am I right?
 
The electrodes don't have to be electrically neutral, and generally won't be - the webpage gives example reaction relations.
So how do you understand redox reactions working?
 
In redox reaction one atom loses electrons and another atom gains electrons.
Is it possible for a redox reaction to occur just by simply placing atoms of zinc and copper together or we need to have an oxidizing/reducing agents for this to happen?
 
My question is. Will the following reaction happen if there was no solution.
Zn(s) + Cu2+(aq)
doublearrow.gif
Zn2+(aq) + Cu(s)
I suspect there should be some energy given off which will make electrons pop from the Zn nucleus. Is the attraction between the positively charged Copper ion and Zn atom is enough to make them move??
 
From Wikipedia:
metallic zinc at the surface of the zinc electrode is dissolving into the solution
Can you explain what makes them dissolve into the solution? The solution is just a mix of Zn2+ and SO42-. Do Zn atoms react with Zn2+ or S042- ?
 

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