Well, I don't know what an "example" would be for the standard proof of the halting problem's noncomputability. If you want the proof itself you can find it on wikipedia.
For an example of a program which may or may not halt, consider the 3n + 1 problem. (find an explanation at http://acm.uva.es/p/v1/100.html) . Now write a program which does the following:
i <- 0
start:
i <- i + 1
run the 3n + 1 algorithm starting from i until one of the following two things happen:
if the sequence entered a finite loop of numbers that repeat over and over and do not include 1, return 0
otherwise if the sequence generated by that algorithm terminated in 1, goto start
You can turn any unsolved problem in mathematics into this kind of "example" of the halting problem. For example you could do: "Iterate through all legal proofs in ZFC. If one of them is a proof for Goldbach's conjecture, return 0. Otherwise keep iterating."